Matrix isolation evidence from [ ( T ~-C ~H ~) W ( C O ) ~N O ]( l a ) and its labelled analogues containing 13CO, ( 2 8 0 , or N180indicates an intramolecular CO attack at the nitrogen of a NO ligand in the photochemical formation of a group 6 metal isocyanato-species.
Solution and Matrix Photochemistry of the lsoelectronic Series of' Half -sandwich ' Carbonyl(q6-cyclopentadienyl)nitrosyl Complexes of Manganese, Chromium, and Vanadium, [ M(q'-C,H,)(CO)3-n( NO),] ( n = 0,
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