A novel method for the synthesis of bile-acid-based polymers has been developed using click chemistry. These 1,2,3-triazole-containing polymers have been found to stabilize silver nanoparticles that show selective colorimetric sensing for iodide ion.
A novel method for the synthesis of a bile acid-based macrocycle has been developed using click chemistry. The 1,2,3-triazolium derivative of the macrocycle shows remarkable selectivity in binding of chloride ion.
In this work, we incorporate titanium dioxide (TiO2) particles as fillers into room temperature vulcanized silicone rubber (RTV-SR) and fabricated the RTV-SR/TiO2 composites. Herein, the effect of various surface areas of TiO2 particles on the mechanical properties of RTV-SR/TiO2 composites was investigated. The particle size of different types of TiO2 particles (147 nm, 34 nm, and 29 nm) was measured by using scanning electron microscopy (SEM), whereas the Brunauer–Emmett–Teller (BET) surface area was measured through adsorption-desorption isotherms as 3, 50, and 145 m2/g, respectively. TiO2 particles reinforced RTV-SR composites were prepared by solution mixing method. TiO2 particles with smaller particle sizes and high BET surface area exhibited higher mechanical properties. The compressive moduli were obtained as 2.2 MPa for a virgin sample and increased to 2.6 MPa, 2.8 MPa and 3.24 MPa for 3, 50, and 145 m2/g samples respectively at 6 phr filler loading. Similarly, the fracture strain of the composite was 117% for a virgin sample and changed to 94%, 130%, and 205% for 3, 50, and 145 m2/g samples, respectively, at 8 phr filler loading. The surface area and particle size of the fillers showed significant effect on mechanical properties of the composites, but no significant effect was observed on the energy harvesting values of RTV-SR/TiO2 composites.
Bile acid-based 1,2,3-triazole ligands have been synthesized, which show excellent ability to stabilize silver nanoparticles. These AgNPs have been found to exhibit highly selective dual colorimetric sensing of Hg2+ and I− ions.
Molecular recognition properties are reported for novel bile acid-based receptors that incorporate 2,6-diaminopyridine as a recognition unit. Apart from hydrogen-bonding interactions, the bile acid receptors exhibit significant aromatic π-stacking interactions with the aromatic fused ring of the flavin derivative. These studies provide rationalisation for the differences in binding behaviour of bile acid receptors having differing aromatic arm lengths towards a flavin analogue.
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