Electrochemical water oxidation catalyzed by a homogeneous Ni–NHC/pyridine complex demonstrated electrolyte-dependent catalytic performances. The catalyst displayed a stable catalytic current of oxygen evolution in long-term bulk electrolysis.
Metal-organic frameworks (MOFs) are not much investigated as catalysts in copolymer formation with cyclic esters. Herein, we report the ring-opening copolymerization of -caprolactone (CL) with δ-valerolactone (VL) using a recoverable...
Here, for the first time, a 2D and leaf-like zeolitic imidazolate framework (ZIF-L) is reported for the synthesis of ultrahigh molecular weight (UHMW) poly(methyl methacrylate) (PMMA) with Mn up to 1390 kg mol−1. This synthesis method is a one-step process without any co-catalyst in a solvent-free medium. SEM, PXRD, FT-IR, TGA, and nitrogen sorption measurements confirmed the 2D and leaf-like structure of ZIF-L. The results of PXRD, SEM, TGA demonstrate that the catalyst ZIF-L is remarkably stable even after a long-time polymerization reaction. Zwitterionic Lewis pair polymerization (LPP) has been proposed for the catalytic performance of ZIF-L on methyl methacrylate (MMA) polymerization. This MMA polymerization is consistent with a living system, where ZIF-L could reinitiate the polymerization and propagates the process by gradually growing the polymer chains.
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