Unlike electronics, optics do not follow Moore's law. This statement, expressed by Microsoft's Bernard Kress, refers to the hard challenges to solve in augmented reality hardware. While light sources have undergone numerous revolutions from candles to light emitting diodes, the evolution in transparent optics has been much slower. For transparent materials, variation of the shape, bulk refractive index, and/or its distribution leads to control of the transmitted beam in an optical system. An alternative, the control of the optical axis orientation in an anisotropic material in transparent micrometer‐thin films on a variety of substrates, is explored here. In contrast to metamaterials, these diffractive waveplates have a continuous structure allowing multilayer/multifunctional planar optical systems with close to 100% efficiency across broad bands of wavelengths (ultraviolet to infrared) with customizable spectra. The low‐cost and fast fabrication technology of this fourth generation of optics is scalable to very large aperture sizes. In addition to wearable adaptive optics, the technology enables thin and compact non‐mechanical fast beam steering systems for light detection and ultralight space telescopes. This review will first serve as an introduction to these unique transparent, planar optical films, and then recent advances enabled by specific optical designs will be presented.
A different generation of polymer-dispersed liquid crystals (PDLCs) based on a liquid crystalline polymer host is reported wherein the fluid behavior of the reactive mesogenic monomer is an enabler to concentration windows (liquid crystal polymer/liquid crystal) (and subsequent morphologies) not previously explored. These liquid crystal (LC) polymer/LC composites, LCPDLCs, exhibit excellent optical and electro-optical properties with negligible scattering losses in both the ON and OFF states. These systems thus have application in systems where fast phase modulation of optical signal instead of amplitude control is needed. Polarized optical microscopy and high resolution scanning electron microscopy confirm a bicontinuous morphology composed of aligned LC polymer coexisting with a phase separated LC fluid. Operating voltages, switching times, and spectra of LCPDLCs compare favourably to conventional PDLC films. The LCPDLCs exhibit a low switching voltage (4–5 V/μm), symmetric and submillisecond (200 μs) on/off response times, and high transmission in both the as formed and switched state in a phase modulation geometry.
Cholesteric liquid crystals (CLCs) are selectively reflective optical materials, the color of which can be tuned via electrical, thermal, mechanical, or optical stimuli. In this work, we show that self-regulation of the transmission of a circularly polarized incident beam can occur upon phototuning of the selective reflection peak of a photosensitive CLC mixture towards the pump wavelength. The autonomous behavior occurs as the red-shifting selective reflection peak approaches the wavelength of the incident laser light. Once the red-edge of the CLC bandgap and incident laser wavelength overlap, the rate of tuning dramatically slows. The dwell time (i.e., duration of the overlap of stimulus wavelength with CLC bandgap) is shown to depend on the radiation wavelength, polarization, and intensity. Necessary conditions for substantial dwell time of the CLC reflection peak at the pump beam wavelength include irradiation with low intensity light (~1mW/cm²) and the utilization of circularly polarized light of the same handedness as the helical structure within the CLC. Monitoring the optical properties in both reflection and transmission geometries elucidates differences associated with attenuation of the light through the thickness of the CLC film.
Scattering-free liquid crystal polymer-dispersed liquid crystal polymer (LCPDLC) films are fabricated by combining a room temperature polymerizable liquid crystal (LC) monomer with a mesogenic photosensitive LC. The morphological and photosensitive properties of the system are analysed with polarized optical microscopy and high resolution scanning and transmission electron microscopy. A two-phase morphology comprised of oriented fibril-like polymeric structures interwoven with nanoscale domains of phase separated LC exists. The nanoscale of the structures enables an absence of scattering which allows imaging through the LCPDLC sample without optical distortion. The use of a mesogenic monomer enables much smaller phase separated domains as compared to nonmesogenic systems. All-optical experiments show that the transmitted intensity, measured through parallel polarizers, can be modulated by the low power density radiation (31 mW/cm 2) of a suitable wavelength (532 nm). The reversible and repeatable transmission change is due to the photoinduced trans-cis photoisomerization process. The birefringence variation (0.01) obtained by optically pumping the LCPDLC films allow their use as an alloptical phase modulator.
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