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We present the first experimental comparison of effective single mode operation bandwidth in sub-wavelength optical wires (SOWs) and conventional single-mode fibers (SMFs). The full transmission spectrum, half-turn bend loss and mode field diameter were measured and compared for a variety of SMFs of different cutoff wavelength and a SOW. The SOW was shown to offer an enormously broadband single-mode operation bandwidth with a larger mode field area than the SMFs. Applications of SOWs include fiber lasers, sensors, photolithography and optical coherence tomography amongst others.

In conventional photolithography, diffraction limits the resolution to about one-quarter of the wavelength of the light used. We introduce an approach to photolithography in which multiphoton absorption of pulsed 800-nanometer (nm) light is used to initiate cross-linking in a polymer photoresist and one-photon absorption of continuous-wave 800-nm light is used simultaneously to deactivate the photopolymerization. By employing spatial phase-shaping of the deactivation beam, we demonstrate the fabrication of features with scalable resolution along the beam axis, down to a 40-nm minimum feature size. We anticipate application of this technique for the fabrication of diverse two- and three-dimensional structures with a feature size that is a small fraction of the wavelength of the light employed.

Molecular dynamics simulations and vibrational sum frequency generation (VSFG) experiments in the methyl-stretching spectral region have been used to study acetonitrile at the silica/liquid, silica/vapor, and liquid/vapor interfaces. Our simulations show that, at the silica/liquid interface, acetonitrile takes on a considerably different structure than in the bulk liquid. The interfacial structure is reminiscent of a lipid bilayer, and this type of ordering persists for tens of Ångstroms into the bulk liquid. This result has important implications for processes involving solid/acetonitrile interfaces, such as heterogeneous catalysis and chromatographic separations. Fitting of VSFG data that have an extremely low nonresonant background contribution provides strong evidence for interfacial populations pointing in opposite directions at these interfaces, in agreement with our simulations. The picture developed from our simulations and experiments reconciles conflicting interpretations of data from previous experimental studies of interfacial acetonitrile.

We report on the assembly of low-loss silica nanowires into functional microphotonics devices on a low-index nondissipative silica aerogel substrate. Using this all-silica technique, we fabricated linear waveguides, waveguide bends, and branch couplers. The devices are significantly smaller than existing comparable devices and have low optical loss, indicating that the all-silica technique presented here has great potential for future applications in optical communication, optical sensing, and high-density optical integration.