Recent progress in reverse osmosis (RO) technology is not limited to RO membrane materials, module designs and RO process optimization. It involves prior feed treatment which directly impacts RO system performance. The ongoing challenges of membrane fouling in RO membranes can be addressed by increasing the operational efficiency through the use of correct pretreatment options which can mitigate organic and inorganic fouling by selectively rejecting contaminants prior to reaching the RO unit. Highly polluted water resources have put critical stress on the existing conventional pretreatment techniques, whereby membrane pretreatment has emerged as a promising alternative. This paper provides an overview of the development and current trends in conventional and nonconventional RO pretreatment techniques whereby the techniques are critically reviewed to 2 inform readers of potential improvements in such areas. This paper addresses the major drawbacks of conventional pretreatment methods which have necessitated the use of membrane pretreatment techniques. Special attention is given to microfiltration, ultrafiltration and nanofiltration methods and their development in terms of advanced membrane materials based on ceramics and self-cleaning membranes. Studies from laboratory scale standalone systems, pilot scale and large scale integrated systems for performance, cost and ecological analysis have been reviewed to familiarize readers with the many factors which need to be analyzed for selection of the appropriate pretreatment method(s). The critical review in this paper will help researchers focus more on the areas which have room for further development for cost-effective and advanced RO pretreatment techniques.
Growing water demands have led to rapidly increasing desalination installation capacity worldwide. In an attempt to lower carbon footprint resulting from high-energy consuming desalination processes, attention has shifted to using renewable energy sources to power desalination. With solar irradiation ample in regions that heavily rely on desalination, solar powered desalination provides a sustainable solution to meeting water needs. The compatibility of each desalination process with the solar technology is driven by whether the kind of energy needed is thermal or electrical, as well as its availability. With rapid advances in solar energy technologiesboth photovoltaic and solar thermal, there has also been growing interest in coupling solar energy with desalination, with a focus on improving energy efficiency. In this review, the most recent developments in photovoltaic powered reverse osmosis (PV-RO), solar thermal powered reverse osmosis (ST-RO) are discussed with respect to membrane materials, process configuration, energy recovery devices and energy storage. In addition, advances in new materials for solar powered membrane distillation (MD) and solar stills in the past two years have also been reviewed. Future outlook considers the use of hybrid renewable energy systems as well as solar powered forward osmosis and dewvaporation. Solar powered desalination systems have been analysed with emphasis on technological and energy consumption aspects.
Hydrophobic PVDF-HFP nanowebs were fabricated by a facile electrospinning method and proposed for harvesting fog from the atmosphere. A strong adhesive force between the surface and a water droplet has been observed, which resists the water being shed from the surface. The water droplets on the inhomogeneous nanomats showed high contact angle hysteresis. The impregnation of nanomats with lubricants (total quartz oil and Krytox 1506) decreased the contact angle hysteresis and hence improved the roll off of water droplets on the nanomat surface. It was found that water droplets of 5 μL size (diameter = 2.1 mm) and larger roll down on an oil-impregnated surface, held vertically, compared to 38 μL (diameter = 4.2 mm) on a plain nanoweb. The contact angle hysteresis decreased from ~95 to ~23° with the Krytox 1506 impregnation.
The utilization of seawater for drinking purposes is limited by the high specific energy consumption (SEC) (kW-h/m 3 ) of present desalination technologies; both thermal and membranebased. This is in turn exasperated by high water production costs, adding up to the water scarcity around the globe. Most technologies are already working near their thermodynamic limit, whilst posing challenges in further SEC reductions. Understanding the current energy status and energy breakdowns of leading desalination technologies will further help in realizing limitations and boundaries imposed while working for improved system performances. This paper comprehensively reviews the energy requirements and potential research areas for reduced SEC of various thermal, membrane-based and emerging desalination technologies. For thermal desalination processes, which consume a large chunk of energy for heating, renewable energy sources can be a viable option for bringing down the energy requirements. Hence, this review also focuses on the potential of desalination-renewable energy integrations. The review extends beyond conventional energy reduction possibilities to utilizing novel, advanced membranes and innovative techniques for energy offsets. The future of desalination for optimized energy requirements is projected to include ultra-high permeability membranes, fouling resistant membranes, hybrid systems, and renewable-energy driven desalination.
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