A variety of mixed metal oxides (MMOs), containing alkali, alkaline, rare earth and noble metals, and their applications are presented. In this mini review, we summarize versatile applications of mixed metal oxides in organic synthesis. A variety of reactions such as reduction,
Reduction by magnetic nano-Fe(3)O(4)-Ni: a facile, simple and environmentally friendly hydrogen-transfer reaction that takes place over recyclable ferrite-nickel magnetic nanoparticles (Fe(3)O(4)-Ni) by using glycerol as hydrogen source allows aromatic amines and alcohols to be synthesized from the precursor nitroarenes and carbonyl compounds.
Nano‐MgO/ZrO2 is prepared and used as catalyst for cross‐aldol condensation, Cbz‐protection of amines, reduction of aromatic nitro compounds and the synthesis of 1,5‐benzodiazepines.
[reaction: see text] [corrected] Regio- and chemoselective reduction of nitroarenes and carbonyl compounds and reductive cleavage of azo compounds, including bulkier molecules, was achieved by the catalytic transfer hydrogenation method (CTH) using a novel nickel-containing mesoporous silicate (NiMCM-41) molecular sieve catalyst. In addition, the catalyst was also found to behave as a truly heterogeneous catalyst as the yield was practically unaffected.
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