Generally the methods were used to characterize soil contamination include collecting samples of soil then analyzing them to recognize contaminates in the laboratory. Commonly, this method of characterizing the contamination of a soil system is the only one agreeable to regulatory societies. However, sample analysis in the lab faces important problems such as soils sampling is really time consuming and costly, sampling is not constant with time and the samples be able to contaminate through sampling and carrying to the lab. Thus several geophysical techniques have been developed which used the dissimilarity in the soil physical properties after soil contamination. Dielectric technique shows high conceivable for characterization diesel contaminated soil. Further use of this technique; rely upon the availability of information about the dielectric properties of the contaminated soil. In this study, the effects of induced by a diesel presence in an unsaturated soil, on the complex dielectric properties were sought. It has been shown experimentally that the diesel presence in an unsaturated soil is traduced by an increase of both dielectric constant and loss factor. A comparison with the existing results in this study and in the literature for saturated soils shows an opposite effect on the complex dielectric properties. The importance of the influence induced by the diesel on the dielectric properties of an unsaturated soil was noticed and compared to a saturated soil. On the basis of the theoretical dielectric mixture models, a justification to these opposite behaviors and their importance has been presented and various models for the two cases have been developed.
This paper presents the development of an electromagnetic probe to accurately measure the soil electromagnetic properties such as dielectric constant and loss factor in the field. The in-site dielectric probe sensor is designed and methods have been developed to calibrate and validate the accuracy of the sensor in measuring dielectric properties of the material. Clean saturated sandy soil material with porosity 40% was used. The soil samples were contaminated by leachate from municipality solid waste from the landfill site. Five levels of leachate contamination were prepared, ranging from 0% to 10%. Dielectric properties of soil polluted sample were measured using the proposed in-site dielectric sensor. Dielectric properties of contaminated soil were evaluated at a different frequency and leachate content. The result showed that both dielectric constant and loss factor decree with increasing frequency due to the reduction of conductance current at high frequency. Also, the result showed that the dielectric properties of leachate-contaminated soil decrease with increasing leachate content while the loss factor increase with increasing leachate content. Mathematical models were developed to determine the relationship between soil dielectric constant, loss factor and soil leachate pollution content.
This paper presents a new method of dielectric capacitance cell as a proposed device for measuring the impedance of pure sand artificially contaminated with four heavy metals. Dielectric constant and loss factor of clean and contaminated sand at various levels were calculated from the measured sand impedances. The advantages and benefits of using the proposed dielectric capacitance cell were its low cost, simple calculation, calibration procedures, portable and lightweight, and easy to modify the electrodes to suit testing in the field. Pure sand was saturated with water artificially polluted in the lab with Pb, Cd, Fe, and Zn at heavy metal contents 0, 7.5, 15, 22.5, and 30 mg/kg of sand. The dielectric properties of polluted sand were evaluated at a frequency range from 100 kHz to 1000 kHz. The polluted sand exhibit different dielectric constants and loss factors from the unpolluted sand. The results also indicate that the dielectric constant decreases with increasing pollution level for all heavy metals. This may attribute to the polarization mechanism change with existing heavy metal. The loss factor of sand increases with the increasing pollution level. This may be explained by the increase of ionic conductivity of pore water with heavy metal in the sand. Sand polluted with heavy metal with higher resistivity and density possess a higher dielectric constant and lower loss factor than other polluted metals. Evaluation of the dielectric characteristics of polluted sand could have the potential to monitor heavy metal pollution. Even with promising results obtained with the proposed dielectric device, it is necessary to explore several other factors affecting the measurements such as sand water content, soil texture, and type of soil. Also, testing polluted soil near industrial pollution is needed.
Incorporating pigments into polymers can be done for various purposes, including the introduction of color, interfacial effects, or aesthetics. If these pigments are to disperse properly, then the process of extrusion must be optimized. During polymer compounding extrusion, three effective processing factors were investigated: feed rate (FR), speed (Sp.) and temperature (temp.) for a colored compounded polycarbonate (PC) grade (30/70%). The processing design techniques were obtained by applying design experiments in a response surface methodology (RSM) to blend two polycarbonates with pigments and optimize the processing temperatures at center points. The first study decided to utilize the response surface approach of Box–Behnken design (BBD) to design an experiment to optimize the process parameters. Statistical significance was demonstrated by the model passing all diagnostic tests. Furthermore, the three processing factors strongly impacted the characteristics of the tri-stimulus color, according to the results from a variance analysis. The second study identified process variables for the same PC grade at the center level, 25 kg/h FR, 750 rpm speed, and (255 °C) temp. The characterization and scanning morphology were examined using MicroCtscanner image analysis, SEM, DOM, rheology, FT-IR, and color-pigmented values were measured using a color spectrometer. The output response was significantly impacted when excellent color dispersion was observed with few agglomerates and less differences in colors at the center point. By characterizing these results and having good insight into color difference output and processing condition relationships, which have an adverse effect on color variation characteristics and minimize recycling compounds of different grades, results in cleaner environments benefits.
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