The crystal structures of CusZn8, CusCds and FeaZna0 have been studied using single-crystal X-ray diffraction techniques. All three alloys have the body-centred cubic space group 1743m with four formula units per unit cell. Lattice parameters are 8.878 (4), 9.615 (10) and 9.018 (3) A respectively for CusZn8, CusCd8 and the pseudocell of FeaZn~0. Evidence shows a new superstructure of 36 A at the composition FeaZn~0. Values of lattice parameter as a function of composition are given for the CusCd8 phase. New data are presented on the three structures, and the ordering of the alomic species is compared with that reported by previous workers. Significant differences in our ordering for FeaZn~0 are attributed to our different composition within the 7 phase. X-ray diffraction intensity data were collected using a 3-circle automatic single-crystal diffractometer and Mo Ke X-radiation. The crystal structures were refined using full-matrix least-squares methods to final R values of 6.1%, 7-5 %, and 5.5 % respectively. A discussion of possible reinterpretations for these and other ~, brass structures is presented.

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