Thermoluminescence (TL) age determinations of alluvial sediments in the tropics are evaluated by comparison with U/Th age determinations of pedogenic accumulations in the alluvium of the lower Gilbert River, a large fan delta in the wet-dry tropics of northern Queensland, Australia. This study extends U/Th dating by applying it not only to calcretes, but also to Fe/Mn oxyhydroxide/oxide accumulations. While a direct correlation cannot be made between U/Th dates from secondary minerals and TL dates from the host sediments, both sets of data show broad consistency. In addition to providing a minima for acceptable TL ages, U/Th dates are useful for determining the chronology of pedogenesis/diagenesis. They show that calcretes and ferricretes have formed under similar climatic conditions in the wet-dry tropics of northern Australia during the late pleistocene. Beneath about 5–12 m the Gilbert fan delta consists of an extensive sand body older than 85,000 yr and probably about 120,000 yr in age, representative of a period of major fluvial activity not repeated since this time. Above are muds and fine sandy muds that extend uninterrupted to the present surface except in the downstream fan where they are bisected by a thin unit of medium sand that TL dates at 40,000–50,000 yr B.P. A system of sandy distributary channels over the fan surface represents an early Holocene fluvial phase probably more active than at present.
In the coastal region, the highest magnitude storms cannot always be invoked to account for large-scale, anomalous sediment features. Any coastline in the Pacific Ocean region can be affected by tsunamis, including Australia which historically lacks evidence of such events. Geologically, tsunamis along the New South Wales coast have deposited a suite of Holocene features that consist of anomalous boulder masses, either chaotically tossed onto rock platforms and backshores or jammed into crevices; highly bimodal mixtures of sand and boulders; and dump deposits consisting of well sorted coarse debris. In addition many coastal aboriginal middens were disturbed by such events. Within estuaries, tsunamis have left a record of stranded run-up ridges which have been interrupted mistakenly as cheniers. Dating of such deposits indicates that several events have affected this coastline since 3000 BP. In contrast to storm waves, tsunamis can leave a depositional imprint of their passage that is characterized by chaotic sorting and mixing of sediments either from different coastal environments or of different sediment sizes. The preservation potential of these deposits is high where sediments have been deposited above present sea-level or stranded inland.
Sand barriers along the coast of southern New South Wales, dating from the last interglacial, have been almost completely destroyed, most probably by a catastrophic tsunami. Evidence for catastrophic wave erosion can also be traced to heights of at least 15 m above present sea level on coastal abrasion ramps. These erosional features lie above the range of effective erosion by contemporary storm waves, and cannot be attributed to either eustatic fluctuations or local uplift. Chronological evidence for the timing of the destruction of the last interglacial barriers suggests that tsunami generated by the submarine slide off Lanai in the Hawaiian Islands 105 ka traveled across the Pacific and eroded this coast.
Loss of deuterium label during the LC step in amide hydrogen/deuterium exchange mass spectrometry (H/D-MS) is minimized by maintaining an acidic mobile phase pH and low temperature (pH 2.5, 0°C). Here we detail the construction and performance of a low-cost, thermoelectrically refrigerated enclosure to house high-performance liquid chromatography (HPLC) components and cool mobile phases. Small volume heat exchangers rapidly decrease mobile phase temperature and keep the temperature stable to ±0.2°C. Using a superficially porous reversed-phase column, we obtained excellent chromatographic performance in the separation of peptides with a median peak width of 4.4 s. Average deuterium recovery was 80.2% with an average relative precision of 0.91%.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.