The occurrence of nitrogenous compounds in industrial effluents at concentration levels above legal limits, is a well-known and serious pollution problem for the receiving body. The biological process for the removal of these substances, commonly referred to as ammoniacal nitrogen, is known as nitrification. Bacteria involved are mainly of the genuses Nitrosomonas and Nitrobacter. The aim of the present work was to study the effect of the hydraulic retention time (HRT) on the efficiency of ammonia removal from a petroleum refinery effluent using activated carbon particles as a biofilm support in an airlift bioreactor. The experiments were carried out using HRTs, equal to six, eight and ten hours. The results show that HRT equal to 8 and 10 hours were enough to reduce ammoniacal nitrogen concentration to levels below permited legal limits (5mg/L NH3-N). The reactor nitrifying performance was maximized at 85% removal of ammoniacal nitrogen, for a HRT equal to 10 hours
- An Aerated Submerged Biological Filter was used to promote biological nitrification of a synthetic saline wastewater. Black PVC corrugated plates were used to make the structured packing of the 6 liter reactor. Nitrate, nitrite, and ammonia concentrations, pH and DO were periodically measured, according to APHA (1985). In spite of the deleterious effect of salinity, it was possible to obtain nitrogen removal efficiencies as high as 95% for a 25 g/L salt concentration after a three-day reaction in the batch reactor. Continuous operation using a NaCl concentration of 25 g/L was tested using three different hydraulic retention times: 7, 15, and 25 hours. An increase in ammonia removal was observed when the retention time was increased from 7 to 15 hours. However, no further notable increase was obtained for a 25 hour retention time, showing that nitrogen removal tends towards a maximum limit of about 80%
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