Carbonate rocks have become very important in Brazil with pre-salt reservoir discoveries in Santos and Campos Basins. Since then, great efforts in research and technology have been made to characterize and develop these reservoirs. In this sense, outcrop analogue studies have become a powerful tool for helping the recognition of geological heterogeneities responsible for controlling the fluid flow in hydrocarbon reservoirs. Besides that, pre-salt oil recovery is associated with high carbon dioxide (CO 2) production, and due environmental issues, it is required a sustainable destination for this contaminant. CO 2 injection in the reservoir, either pure or mixed to the produced gas stream, could be a good manner to deal with this undesirable component and increase the oil recovery. This work uses outcrop analogue characterization to understand how carbonate reservoir characteristics impact the selection of the best recovery strategy under Brazilian-pre-salt-like conditions. Numerical simulation models were run using the flow simulator TEMPEST MORE (version 7.1) with isothermal compositional modeling. The oil recovery process was modeled by continuous and alternating injection of CO 2 and water. The recovered oil fractions for the simulation case with water alternating CO 2 injection were higher than with the use of continuous injection of CO 2 or water.