The refractory tungsten alloys with high ductility/strength/plasticity are highly desirable for a wide range of critical applications. Here we report an interface design strategy that achieves 8.5 mm thick W-0.5 wt. %ZrC alloy plates with a flexural strength of 2.5 GPa and a strain of 3% at room temperature (RT) and ductile-to-brittle transition temperature of about 100 °C. The tensile strength is about 991 MPa at RT and 582 MPa at 500 °C, as well as total elongation is about 1.1% at RT and as large as 41% at 500 °C, respectively. In addition, the W-ZrC alloy plate can sustain 3.3 MJ/m2 thermal load without any cracks. This processing route offers the special coherent interfaces of grain/phase boundaries (GB/PBs) and the diminishing O impurity at GBs, which significantly strengthens GB/PBs and thereby enhances the ductility/strength/plasticity of W alloy. The design thought can be used in the future to prepare new alloys with higher ductility/strength.
Abstract. The Tibetan Plateau (TP), referred to as the "roof of the world", is also known as the "world water tower" because it contains a large amount of water resources and ceaselessly transports these waters to its surrounding areas. However, it is not clear how these waters are being supplied and replenished. In particular, how plausible hydrological cycles can be realized between tropical oceans and the TP. In order to explore the mechanism sustaining the atmospheric "water tower" over the TP, the relationship of a "heat source column" over the plateau and moist flows in the Asian summer monsoon circulation is investigated. Here we show that the plateau's thermal structure leads to dynamic processes with an integration of two couplings of lower convergence zones and upper divergences, respectively, over the plateau's southern slopes and main platform, which relay moist air in two ladders up to the plateau. Similarly to the CISK (conditional instability of the second kind) mechanism of tropical cyclones, the elevated warm-moist air, in turn, forces convective weather systems, hence building a water cycle over the plateau. An integration of mechanical and thermal TP forcing is revealed in relation to the Asian summer monsoon circulation knitting a close tie of vapor transport from tropical oceans to the atmospheric "water tower" over the TP.
Abstract. Recent studies have suggested that deserts, which are a long-neglected region in global carbon budgeting, have strong downward CO2 fluxes and might be a significant carbon sink. This finding, however, has been strongly challenged because neither the reliability of the flux measurements nor the exact location of the fixed carbon has been determined. This paper shows, with a full chain of evidence, that there is indeed strong carbon flux into saline/alkaline land in arid regions. Based on continuous measurement of net ecosystem CO2 exchange (NEE) from 2002 to 2012 (except for 2003), the saline desert in western China was a carbon sink for 9 out of 10 years, and the average yearly NEE for the 10 years was −25.00 ± 12.70 g C m−2 year−1. Supporting evidence for the validity of these NEE estimates comes from the close agreement of NEE values obtained from the chamber and eddy-covariance methods. After ruling out the possibility of changes in C stored in plant biomass or soils, the C uptake was found to be leached downwards into the groundwater body in the process of groundwater fluctuation: rising groundwater absorbs soil dissolved inorganic carbon (DIC), and falling groundwater transports the DIC downward. Horizontal groundwater flow may send this DIC farther away and prevent it from being observed locally. This process has been called "passive leaching" of DIC, in comparison with the active DIC leaching that occurs during groundwater recharge. This passive leaching significantly expands the area where DIC leaching occurs and creates a literally "hidden" carbon sink process under the desert. This study tells us that when a downward CO2 flux is observed, but seems to have nowhere to go, it does not necessarily mean that the flux measurement is unreliable. By looking deeper and farther away, a place and a process may be found "hidden" underground.
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