Increased acts of international terrorism called for the development of rapid and reliable chemical agent decontamination reactions to minimize human exposure and material loss. Even though many chemical reaction processes have been reported, most remain unattractive for various reasons. In order to eliminate many of the adversities, these processes were studied in an ionic liquid solvent. In this report, we describe the reaction between chemical warfare simulants with alcohols in the ionic liquid 1,2-dimethyl-3-propylimmidazolium bis(trifluoromethylsulfonyl)amide made basic with tetramethylammonium hydroxide pentahydrate. The chemical agent simulants used in this study were diisopropylfluorophosphate, bis(2-ethylhexyl) phosphite, and chloroethylphenyl sulfide, which simulate agents GD, VX, and HD, respectively. The reactions were rapid, and products were identified by LC/MS-TOF and GC/MS. All of the reaction products of the VX and HD simulants remained in the ionic liquid, whereas the products from GD simulant partitioned between the ionic liquid and water extract.
Titanium alloys such as A-110AT, B-120VCA, C-120AV, and 6-6-2AVT, which have been used to manufacture structural components for the aerospace industry, are difficult to machine when compared to aluminum and even some steel alloys. Tool wear for high-speed tool steel and carbide cutters takes place rapidly, necessitating the use of low cutting speeds and feeds to obtain a reasonable cutter life. In this study, the means used toward achieving an objective of increased producibility and reduced costs for titanium alloys was through an intensive machinability investigation of the machining characteristics. Control of pertinent machining variables, such as cutting speed, feed rate, tool material, tool geometry, machine tool setup, and cutting fluid, was rigorously maintained. Comparative cost analyses of the actual cutting operation and the attendant cutting tool costs were made concurrently with the study to obtain conditions which provided the best metal removal rate with reasonable cutter life at the lowest cost.
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