Solar thermal collectors are emerging as a prime mode of harnessing the solar radiations for generation of alternate energy. Heat transfer fluids (HTFs) are employed for transferring and utilizing the solar heat collected via solar thermal energy collectors. Solar thermal collectors are commonly categorized into low temperature collectors, medium temperature collectors and high temperature collectors. Low temperature solar collectors use phase changing refrigerants and water as heat transfer fluids. Degrading water quality in certain geographic locations and high freezing point is hampering its suitability and hence use of water-glycol mixtures as well as water-based nano fluids are gaining momentum in low temperature solar collector applications. Hydrocarbons like propane, pentane and butane are also used as refrigerants in many cases. HTFs used in medium temperature solar collectors include water, waterglycol mixtures -the emerging "green glycol" i.e., trimethylene glycol and also a whole range of naturally occurring hydrocarbon oils in various compositions such as aromatic oils, naphthenic oils and paraffinic oils in their increasing order of operating temperatures. In some cases, semi-synthetic heat transfer oils have also been reported to be used. HTFs for high temperature solar collectors are a high priority area and extensive investigations and developments are occurring globally. In this category, wide range of molecules starting from water in direct steam generation, air, synthetic hydrocarbon oils, nanofluid compositions, molten salts, molten metals, dense suspension of solid silicon carbide particles etc., are being explored and employed. Among these, synthetic hydrocarbon oils are used as a fluid of choice in majority of high temperature solar collector applications while other HTFs are being used with varying degree of experimental maturity and commercial viability -for maximizing their benefits and minimizing their disadvantages. Present paper reviews the recent developments taking place in the area of heat transfer fluids for harnessing solar thermal energy. Refrigerants/phase changing materials: These are low boiling point but high heat capacity substances used in the solar collectors to transfer heat in applications like solar space cooling and heating, refrigerators, air conditioning, etc [7]. These materials absorb heat from the solar collectors, produce work either by expanding in a turbo-generator of a vapor compression cycle or by dissociating the refrigerant from its absorbent in a vapor absorption cycle [8]. In some of the relatively high temperature applications, higher boiling point refrigerants are used as indirect heat transfer fluids, wherein the heat collected from the solar collectors is transferred to another fluid like water from where the refrigerants pick-up heat to do the required work in the turbo-generators [9,10]. Recent Developments in Heat Transfer

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A simultaneous functionalization and reduction route to prepare stable dispersion of reduced graphene oxide from graphene oxide has been described. Diethanol amine has been introduced for the first time as an environment friendly reducing agent in a simple reflux reaction. Diethanol amine acts as a reducing agent and helps to enhance the stability of dispersion, making hydrogen bonding by virtue of two functional groups. The prepared dispersion of 0.025 mg/mL concentration is stable for months together and has a zeta potential value -45 V at room temperature. UV-Vis study shows peak at 264 nm that is signatory for reduced graphene oxide. TEM images confirm spread thin sheets of graphene of few hundred nanometer lateral dimension. Thermal diffusivity studies suggest nearly 60% enhancement for the dispersion in comparison to base fluid, water. This suggests graphene dispersion is promising for heat transfer applications.

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