Gold nanostructured materials exhibit important size- and shape-dependent properties that enable a wide variety of applications in photocatalysis, nanoelectronics and phototherapy. Here we show the use of superfast dynamic compression to synthesize extended gold nanostructures, such as nanorods, nanowires and nanosheets, with nanosecond coalescence times. Using a pulsed power generator, we ramp compress spherical gold nanoparticle arrays to pressures of tens of GPa, demonstrating pressure-driven assembly beyond the quasi-static regime of the diamond anvil cell. Our dynamic magnetic ramp compression approach produces smooth, shockless (that is, isentropic) one-dimensional loading with low-temperature states suitable for nanostructure synthesis. Transmission electron microscopy clearly establishes that various gold architectures are formed through compressive mesoscale coalescences of spherical gold nanoparticles, which is further confirmed by in-situ synchrotron X-ray studies and large-scale simulation. This nanofabrication approach applies magnetically driven uniaxial ramp compression to mimic established embossing and imprinting processes, but at ultra-short (nanosecond) timescales.

No abstract

SUMMARYRate-dependent behaviour of chalk and other porous rocks has undergone widespread study in geomechanics due to its implications on the performance of engineering structures. We present a ratedependent constitutive model for chalk and other porous rocks with several new features. The model formulation is based on a viscoplastic rate-lines approach in which the axial strain rate depends on the proximity of the stress point to an elliptical reference surface. A non-associated viscoplastic potential surface and an axial scaling algorithm are used to determine the viscoplastic strain components. The model predicts that axial yields stress varies as a power function of applied axial strain rate, as shown by published laboratory data. Comparisons with published experimental data indicate that the model is capable of reproducing observed rate-dependent behaviour of chalk under a variety of loading conditions.

We have developed the design of Thor: a pulsed power accelerator that delivers a precisely shaped current pulse with a peak value as high as 7 MA to a strip-line load. The peak magnetic pressure achieved within a 1-cm-wide load is as high as 100 GPa. Thor is powered by as many as 288 decoupled and transittime isolated bricks. Each brick consists of a single switch and two capacitors connected electrically in series. The bricks can be individually triggered to achieve a high degree of current pulse tailoring. Because the accelerator is impedance matched throughout, capacitor energy is delivered to the strip-line load with an efficiency as high as 50%. We used an iterative finite element method (FEM), circuit, and magnetohydrodynamic simulations to develop an optimized accelerator design. When powered by 96 bricks, Thor delivers as much as 4.1 MA to a load, and achieves peak magnetic pressures as high as 65 GPa. When powered by 288 bricks, Thor delivers as much as 6.9 MA to a load, and achieves magnetic pressures as high as 170 GPa. We have developed an algebraic calculational procedure that uses the single brick basis function to determine the brick-triggering sequence necessary to generate a highly tailored current pulse time history for shockless loading of samples. Thor will drive a wide variety of magnetically driven shockless ramp compression, shockless flyer plate, shock-ramp, equation of state, material strength, phase transition, and other advanced material physics experiments.

This paper presents the results of an integrated laboratory and numerical modelling study on the effect of wellbore deviation and wellbore azimuth on fracture propagation in poorly consolidated sandstone formations. The goal of this project was to develop an understanding of how fractures would transition from single planar fractures to non-planar transverse fractures for fields in the deep-water Gulf of Mexico.The foundation of this work was over 40 fracturing laboratory tests to measure fracture propagation geometries for a range of well deviations, differential horizontal stresses and rock strength. The samples tested were from three outcrops with unconfined compressive strength (UCS) values ranging from 300 -1000 psi. For boreholes having low deviation angles and small differential stresses a vertical single planar fracture was created, aligned with the wellbore, as expected. As the well trajectory and stress contrast increased the fractures became more complex, with transverse turning fractures no-longer aligned with the wellbore.These laboratory results were used to develop and calibrate a new fully-3D finite element model that predicts non-planar fracture growth. The model matches the details of the laboratory tests, including the transition from planar vertical to nonplanar transverse fractures as the well deviation, azimuth and stress differentials increase. After initial model development and calibration was complete a model of a complex case was run before showing any experimental results to the modellers. The model successfully predicted the transverse non-planar results found in the laboratory; this gave us increased confidence in the model as a predictive tool. This work has now been applied with excellent success to four deepwater fields. We have recommended changes in maximum well deviations, performed post-job analyses on wells that had high deviations, and have increased our understanding of the impact of layered formations on fracture growth in these fields.

Thermal imaging is an important, though challenging, diagnostic for shockwave experiments. Shock-compressed materials undergo transient temperature changes that cannot be recorded with standard (greater than ms response time) infrared detectors. A further complication arises when optical elements near the experiment are destroyed. We have designed a thermal-imaging system for studying shock temperatures produced inside a gas gun at Sandia National Laboratories. Inexpensive, diamond-turned, parabolic mirrors relay an image of the shocked target to the exterior of the gas gun chamber through a sapphire vacuum port. The 3000-5000-nm portion of this image is directed to an infrared camera which acquires a snapshot of the target with a minimum exposure time of 150 ns. A special mask is inserted at the last intermediate image plane, to provide dynamic thermal background recording during the event. Other wavelength bands of this image are split into high-speed detectors operating at 900-1700 nm, and at 1700-3000 nm for timeresolved pyrometry measurements. This system incorporates 90-degree, off-axis parabolic mirrors, which can collect low f/# light over a broad spectral range, for high-speed imaging. Matched mirror pairs must be used so that aberrations cancel. To eliminate image plane tilt, proper tip-to-tip orientation of the parabolic mirrors is required. If one parabolic mirror is rotated 180 degrees about the optical axis connecting the pair of parabolic mirrors, the resulting image is tilted by 60 degrees. Different focal-length mirrors cannot be used to magnify the image without substantially sacrificing image quality. This paper analyzes performance and aberrations of this imaging diagnostic.

SUMMARYChalk and other porous rocks are known to behave differently when saturated with different pore fluids. The behavior of these rocks varies with different pore fluids and additional deformation occurs when the pore fluid composition changes. In this article, we review the evidence that behavior in porous rocks is pore-fluid-dependent, present a constitutive model for pore-fluid-dependent porous rocks, and present a compilation of previously published data to develop quantitative relationships between various pore fluids and mechanical behavior. The model proposed here is based on a state parameter approach for weathering and has similarities to models previously proposed for weathering-sensitive rocks in that the values for parameters that characterize material behavior vary as a function of weathering. Comparisons with published experimental data indicate that the model is capable of reproducing observed behavior of chalk under a variety of loading conditions and changes in pore fluid composition.

No abstract