We describe a novel cw millimeter-wave electron spin resonance (ESR) spectrometer designed to operate in the frequency range of 80–200 GHz and in the temperature range of 2.5–300 K, which may be easily scaled to higher frequencies. The spectrometer uses a bimodal reflection cavity coupled to a circular corrugated guide and uses Gaussian quasi-optics for most of the front-end signal processing. This technique has very low insertion loss and allows a number of sophisticated measurement techniques to be employed including induction operation, which significantly reduces the effect of microphonics and stray reflections. A number of examples are given illustrating the sensitivity of the instrument and the advantages of using ESR at high fields.
The anomalous properties of the Kondo lattice are compared with the well behaved Kondo system, CePd. The low-temperature thermal expansion of CePd is in agreement with previous heat capacity data, showing a ferromagnetic transition at and a second transition at 3.5 K probably due to reorientation of the magnetic moments. The Grüneisen factor, calculated from thermal-expansion and heat capacity is , the same as the Grüneisen factor calculated from the pressure dependence and comparable to a previous measurement of . Thermal expansion measurements (in fields of up to 8 T) and ac susceptibility measurements (under pressures of up to 7.33 kbar) have been made on in the temperature range 1.6-40 K. The zero-pressure ac susceptibility measurements confirm that there is an antiferromagnetic transition at , as previously reported. The magnetic contribution to the linear thermal-expansion coefficient of polycrystalline in zero magnetic field has a maximum value near 17 K and becomes small by 29 K. There is no peak in at the Néel temperature. The Néel temperature is found to decrease under pressure at the rate of , which indicates that is a magnetic Kondo lattice (with ) on the right-hand side of the Doniach diagram.
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