The paper describes some water‐treatment processes which have been investigated on a laboratory and pilot‐plant scale for their effectiveness in removing toxic algal cells and the dissolved toxins microcystin‐LR and anatoxin‐a. Oxidation with ozone or potassium permanganate, or treatment by biological activated carbon, were found to be the most effective processes for removal of the dissolved toxins. Chlorination was effective only for the removal of microcystin‐LR. Toxins, contained within algal cells, could be removed effectively by coagulation, clarification and filtration under suitable conditions. Consideration of the structure and properties of micro‐cystin variants suggests that treatments which are suitable for removal of microcystin‐LR and anatoxin‐a should be suitable for removal of other microcystins.
The occurrence of the protozoan parasite Cryptosporidium parvum in water supplies, and the resultant outbreaks of cryptosporidiosis in the UK and USA, have led to concern over the ability of conventional water treatment processes to remove Cryptosporidia from water sources. Large scale pilot plant trials of water treatment have been carried out in the UK to establish the degree of removal that can be achieved by a range of treatment processes, including dissolved air flotation, and to compare the performance of different treatment options. Results from part of these trials are presented in this paper. These results suggest that well operated chemical coagulation based treatment, using either dissolved air flotation or floc blanket clarification, should be capable of achieving removal of Cryptosporidium oocysts of over 99%. There was no evidence of differences in performance between the different types of filter media investigated. The risk of increased Cryptosporidium concentration in the filtered water will increase as filtrate turbidity increases. However, other factors such as high coagulant metal-ion concentration in the filtered water, or a sudden increase in clarified water turbidity, without any increase in filtered water turbidity, may also indicate treatment problems and associated risk from Cryptosporidia. Recycling of backwash waters may also increase the risk.
Reference refractivity values have been derived for the anaesthetic agents halothane, isoflurane, enflurane, sevoflurane and desflurane which are traceable to national measurement standards. A simple method and equation have been derived for the application of these data to the measurement of agent concentration by refractometry. The main instrumental sources of uncertainty associated with this method are discussed and their respective contributions quantified. Agent concentration can be measured routinely at the +/- 1% level of uncertainty using this approach.
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