Poly[(2,vinylene] (DMPPV) of varying conjugation length was synthesized by selective elimination of organic soluble precursor polymers that contained two eliminatable groups, namely, methoxy and acetate groups. These precursor copolymers were in turn synthesized by competitive nucleophilic substitution of the sulfonium polyelectrolyte precursor (generated by the standard Wessling route) using methanol and sodium acetate in acetic acid. The composition of the precursor copolymer, in terms of the relative amounts of methoxy and acetate groups, was controlled by varying the composition of the reaction mixture during nucleophilic substitution. Thermal elimination of these precursor copolymers at 250 °C, yielded partially conjugated polymers, whose color varied from light yellow to deep red. FT-IR studies confirmed that, while essentially all the acetate groups were eliminated, the methoxy groups were intact and caused the interruption in conjugation. Preliminary photoluminescence studies of the partially eliminated DMPPV samples showed a gradual shift in the emission maximum from 498 to 598 nm with increasing conjugation lengths, suggesting that the color of LED devices fabricated from such polymers can, in principle, be fine-tuned.
This paper presents a comparison of the predictive capability of three hydrological models, and a mean ensemble of these models, in a heavily influenced catchment in Peninsular India: GWAVA (Global Water AVailability Assessment) model, SWAT (Soil Water Assessment Tool) and VIC (Variable Infiltration Capacity) model. The performance of the three models and their ensemble were investigated in five sub-catchments in the upstream reaches of the Cauvery river catchment. Model performances for monthly streamflow simulations from 1983–2005 were analysed using Nash-Sutcliffe efficiency, Kling-Gupta efficiency and percent bias. The predictive capability for each model was compared, and the ability to accurately represent key catchment hydrological processes is discussed. This highlighted the importance of an accurate spatial representation of precipitation for input into hydrological models, and that comprehensive reservoir functionality is paramount to obtaining good results in this region. The performance of the mean ensemble was analysed to determine whether the application of a multi-model ensemble approach can be useful in overcoming the uncertainties associated with individual models. It was demonstrated that the ensemble mean has a better predictive ability in catchments with reservoirs than the individual models, with Nash-Sutcliffe values between 0.49 and 0.92. Therefore, utilising multiple models could be a suitable methodology to offset uncertainty in input data and poor reservoir operation functionality within individual models.
The purpose of the present paper is to introduce the basic notions of Soft Čech closure spaces and investigate some separation axioms in Soft Čech closure spaces.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.