We report the results of experiments in which positronium (Ps) atoms, optically excited to Rydberg-Stark states with principal quantum numbers ranging from n = 13 to 19, were transported along the axis of a multiring electrode structure. By applying alternate positive and negative potentials to the ring electrodes, inhomogeneous electric fields suitable for guiding low-field-seeking atoms along the guide axis were generated. The multiring configuration used has the advantage that once the atoms are confined within it appropriate time-varying fields can be generated for deceleration and trapping. However, in this type of structure the possibility of nonadiabatic transitions of the fast (100 km/s) Ps atoms to unconfined high-field-seeking states exists. We show that for typical guiding fields this is not a significant loss mechanism and that efficient Ps transport can be achieved. Our data are in accordance with a Landau-Zener analysis of adiabatic transport through the field minima and Monte Carlo simulations that take into account Ps velocity distributions, electric dipole moments, and lifetimes, as well as the electric-field distributions in the guide.
We report a measurement of the annihilation decay rate of 2 3 S1 positronium (Ps) atoms, Γexp(2 3 S1). Ground state atoms optically excited to radiatively metastable 2 3 S1 states were quenched via Stark mixing by the application of a time-delayed electric field. Rapid radiative decay of the Stark-mixed states to the ground state, followed by self-annihilation, was observed via the annihilation radiation time spectrum, and used to determine the number of excited state atoms remaining at different times, and hence the decay rate. We obtain Γexp(2 3 S1) = 843 ± 72 kHz, in broad agreement with the Zeeman-shifted theoretical value of 890 kHz.
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