KeyWordsColumn liquid chromatography MS detection Quarternary ammonium herbicides Ion trap vs quadrupole Water analysis
SummaryAn ion-trap mass spectrometer for determination of quaternary ammonium herbicides in water samples is evaluated. Implementation of the method previously optimized in a quadrupole mass spectrometer (VG Platform II) in an ion-trap (LCQ) required modifications to the sample inlet of the electrospray source. Quality parameters were established and detection limits, after trace enrichment, ranged 5-50 ng L 1. Good reproducibilities (day-to-day and run-torun) < 12% were obtained. The method was applied to analysis of spiked samples and the results were comparable with those determined using a quadrupole mass spectrometer.
An ion-pair liquid chromatography-mass spectrometry/mass spectrometry method was developed for the determination of chlormequat in fruit samples. A solid-phase extraction cleanup procedure with C18 cartridges was used. Sample preparation was simple and the achieved detection limit (0.03 mg/kg) and quantitation limit (0.08 mg/kg) were below the maximum residue levels legislated by the European Union. The chromatographic separation was performed by using a C8 column and heptafluorobutyric acid as ion pair reagent. The detection was conducted with an electrospray source and an ion trap as a mass analyzer. The reproducibility of the method gave good run-to-run (8–9%) and day-to-day (9–13%) precision values, and its applicability to the determination of chlormequat in pears and grapes, purées, and pear, apple, and grape juices was demonstrated.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.