Baker, S. R., Watmough, S. A. and Eimers, M. C. 2015. Phosphorus forms and response to changes in pH in acid-sensitive soils on the Precambrian Shield. Can. J. Soil Sci. 95: 95Á108. Soil acidification may explain declines in total phosphorus (TP) levels that have been observed in surface waters in central Ontario, Canada, but much of the research on phosphorus (P) mobility in pH manipulated soils has been performed at high P concentrations (i.e., !500 mM). This study investigated P fractionation in acidic (pH 54.6) soils in south-central Ontario and relationships between soil pH and P sorption at relatively low P concentrations to test whether long-term declines in soil pH could have increased soil P sorption. Soils from three forested catchments that vary naturally in soil pH and outlet stream [TP] (0.1Á0.4 mM in 2008) had very similar soil P concentrations and distributions (Hedley fractionation). Only hydrochloric-acid extractable P (i.e., apatite) differed amongst catchments and was greatest at the catchment with the highest stream [TP]. The fraction of P present as labile/ soluble P did not decline with pH as expected and experiments indicated that P sorption at P concentrations between 4.52 and 452.1 mM was insensitive to manipulated solution pH. Soils were, however, able to sorb!90% of P added in sorption experiments at [P] 5452.1 mM. These results suggest that acidification-induced P sorption in upland soils has not contributed to observed decreases in surface water TP concentrations.Key words: Phosphorus, acidification (soil), Hedley fractionation, sorption, Podzols, Ontario (central) Baker, S. R., Watmough, S. A. et Eimers, M. C. 2015. Types de phosphore et re´action de cet e´le´ment aux variations du pH dans les sols du bouclier pre´cambrien sensibles a`l'acidification. Can. J. Soil Sci. 95: 95Á108. L'acidification du sol pourrait expliquer la concentration de phosphore total (PT) plus faible observe´e dans les eaux superficielles du centre de l'Ontario, mais une bonne partie des recherches sur la mobilite´du phosphore (P) dans les sols dont le pH avait e´te´modifie´ont e´teé ffectue´es a`une concentration de P e´leve´e (a`savoir, supe´rieure a`500 mM). La pre´sente e´tude portait sur le fractionnement du P dans les sols acides (pH 54,6) du centre-sud de l'Ontario et sur les liens existant entre le pH du sol et la sorption du P aux concentrations de P relativement faibles. Elle devait e´tablir si l'acidification a`long terme du sol pouvait avoir accru la sorption du P dans le sol. Trois bassins hydrographiques forestiers dont le pH et la de´charge variaient naturellement [PT] (0,1Á0,4 mM en 2008) pre´sentaient une concentration et une distribution tre`s semblables du P dans leur sol (me´thode de fractionnement de Hedley). Seule la concentration de P extractible a`l'acide chlorhydrique (a`savoir, l'apatite) diffe´rait d'un bassin a`l'autre et atteignait un maximum dans le bassin a`la de´charge la plus importante [PT]. La fraction du P correspondant au P labile/soluble ne diminue pas avec le pH comme ...