An iterative inversion technique has been developed that uses the direct P and S wave arrival times from local earthquakes to compute simultaneously a three‐dimensional velocity structure and relocated hypocenters. Crustal structure is modeled by subdividing flat layers into rectangular blocks. An interpolation function is used to smoothly vary velocities between blocks, allowing ray trace calculations of travel times in a three‐dimensional medium. Tests using synthetic data from known models show that solutions are reasonably independent of block size and spatial distribution but are sensitive to the choice of layer thicknesses. Application of the technique to observed earthquake data from north‐central Utah shows the following: (1) lateral velocity variations in the crust as large as 7% occur over 30‐km distances, (2) earthquake epicenters computed with the three‐dimensional velocity structure were shifted an average of 3.0 km from locations determined assuming homogeneous flat layered models, and (3) the laterally varying velocity structure correlates with anomalous variations in the local gravity and aeromagnetic fields, suggesting that the new velocity information can be valuable in acquiring a better understanding of crustal structure.
Electrical conductivity of Sr2-xVMoO6-y (x = 0.0, 0.1, 0.2) double perovskites has been investigated in a reducing atmosphere at temperatures up to 800 °C. This material has a key application in solid oxide fuel cell anodes as a mixed ion and electron conductor. A solid state synthesis technique was used to fabricate materials and crystal structure was verified through x-ray diffraction. Subsequent to conventional sintering in a reducing environment, elemental valence states were indentified through x-ray photoemission spectroscopy on the double perovskite material before and after annealing in a hydrogen environment. Samples exhibited metallic like conduction with electrical conductivities of 1250 S/cm (Sr2VMoO6-y′), 2530 S/cm (Sr1.8VMoO6-y″), and 3610 S/cm (Sr1.9VMoO6-y‴) at 800 °C in 5% H2/95% N2, with a substantial increase in conductivity upon cooling to room temperature. Room temperature electrical conductivity values for Sr1.9VMoO6-y‴ make it a candidate as the highest electrically conductive oxide known. Highly insulating secondary surface phases, Sr3V2O8, and SrMoO4, begin to reduce at 400 °C in a hydrogen environment, as confirmed by X-ray photoemission and thermal gravimetric analysis. This reduction, from V5+ and Mo6+ to lower valence states, leads to a large increase in sample electrical conductivity.
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