We present the magnetic properties of the Noachian Martian breccia NWA 7034. Among the 25 unpaired Martian meteorites studied to date, NWA 7034 has a unique magnetic mineralogy. It contains about 15 wt % of iron oxides as magnetite that has experienced cation substitution and partial alteration to maghemite, with about a quarter of the oxides being pure maghemite. It also contains oxyhydroxides in the form of superparamagnetic goethite. The presence of maghemite and goethite makes NWA 7034 the most oxidized Martian meteorite. The overall magnetic assemblage is partly linked to near-surface hydrothermal alteration. The high concentration of magnetic phases with high laboratory unblocking temperatures makes NWA 7034 a plausible analogue source lithology for the strong magnetization of the Martian Noachian crust. Near-surface hydrothermal alteration can enhance the remanence of Martian rocks and account for local, high magnetic anomalies of shallow source.

The magnetic spinel ferrites, MFe 2 O 4 (wherein 'M' = a divalent metal ion such as but not limited to Mn, Co, Zn, and Ni), represent a unique class of magnetic materials in which the rational introduction of different 'M's can yield correspondingly unique and interesting magnetic behaviors. Herein we present a generalized hydrothermal method for the synthesis of single-crystalline ferrite nanoparticles with 'M' = Mg, Fe, Co, Ni, Cu, and Zn), which can be systematically and efficaciously produced simply by changing the metal precursor. Our protocol can moreover lead to reproducible size control by judicious selection of various surfactants. As such, we have probed the effects of both (i) size and (ii) chemical composition upon the magnetic properties of these nanomaterials using complementary magnetometry and Mössbauer spectroscopy techniques. The structure of the samples was confirmed by atomic PDF analysis of X-ray and electron powder diffraction data as a function of particle size. These materials retain the bulk spinel structure to the smallest size (i.e. 3 nm). In addition, we have explored the catalytic potential of our ferrites as both (a) magnetically recoverable photocatalysts and (b) biological catalysts, and noted that many of our asprepared ferrite systems evinced intrinsically higher activities as compared with their iron oxide counterparts.

Abstract-We present a description of opaque minerals, opaque mineral compositions, magnetic properties, and paleomagnetic record of the Tissint heavily shocked olivine-phyric shergottite that fell to Earth in 2011. The magnetic mineralogy of Tissint consists of about 0.6 wt% of pyrrhotite and 0.1 wt% of low-Ti titanomagnetite (in the range ulv€ ospinel 3-15 magnetite 85-97). The titanomagnetite formed on Mars by oxidation-exsolution of ulv€ ospinel grains during deuteric alteration. Pyrrhotite is unusual, with respect to other shergottites, for its higher Ni content and lower Fe content. Iron deficiency is attributed by an input of regolith-derived sulfur. This pyrrhotite has probably preserved a metastable hexagonal monosulfide solution structure blocked at temperature above 300°C. The paleomagnetic data indicate that Tissint was magnetized following the major impact suffered by this rock while cooling at the surface of Mars from a post-impact equilibrium temperature of approximately 310°C in a stable magnetic field of about 2 µT of crustal origin. Tissint is too weakly magnetic to account for the observed magnetic anomalies at the Martian surface.

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