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The solubility of hydrogen in Pd – Ti and Pd – Zr solid solution alloys containing up to 6.0 at.% Ti and Zr has been measured at temperatures between 273 K and 433 K and hydrogen pressures up to 1000 Torr. The relative partial molar enthalpy, ΔH0H, at infinite dilution for Pd – Ti alloys shows a minor minimum around 4 at.% Ti, in spite of the Pd lattice contraction on Ti substitution. For Pd – Zr alloys the ΔH0H values increase in exothermicity regularly with Zr content. The relative partial molar entropy, ΔS0H, at infinite dilution in both alloy series decreases with the solute contents. The apparent H‐H attractive interactions, g1, in Pd – Ti(Zr) alloys decrease with alloying metal content, and the trend of the g1 value with Ti content is dissimilar to those found for other lattice contracted alloys. The stability of the β‐phase hydride in Pd – Ti alloys decreases with Ti content and the β‐phase hydride in Pd – Zr alloys also becomes less stable with Zr content, albeit by a small amount, despite being a lattice expanded alloy system. Solvus compositions at the αmax phase boundary in both Pd – Ti and Pd – Zr alloys are almost equal at the same alloying compositions of each alloy series, although increasing with alloying metal content in both cases.

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Time-resolved resonance Raman spectroscopy of the lowest energy excited state of the 4,4'-bipyridyl ligandbridged complex, [(CO)5W(L)W(CO5] (l), and Raman spectroscopy of electrochemically reduced 1, both give bands characteristic of the the L'-species. This confirms that the ligand L is negatively charged in the lowest energy exicited state which is therefore metal-ligand charge transfer (MLCT) in character. Raman spectra of the radical anion of 1 excited in the far red (800 nm) exhibited a band near 2050 cm-' due to a vco symmetric CO stretching mode, compared to the corresponding band at 2070 cm-' in the spectrum of the parent, uncharged complex. The lower vco in the reduced complex supports the recent finding by timeresolved IR spectroscopy of a similar frequency decrease for YCO in the longest lived (MLCT) excited state of 1 which was attributed to electronhole localisation in this state on the IR time scale.

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