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A new 3-D open-framework cadmium borovanadate with 6-connected topology was hydrothermally obtained and structurally characterized. It not only features new cadmium(II) borovanadate which possesses an open-framework structure with unique plane-shaped channels, but also exhibits interesting absorption properties and high catalytic activities for the oxidation of cyclohexanol.

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Insufficient separation of photogenerated electron−hole and feeble CO 2 activation remain the main obstacles in the access to high-performance CO 2 reduction nowadays. Single-atom active sites engineering could be an efficient method through simultaneously promoting charge separation and CO 2 activation. Herein, a model of Bi 4 O 5 I 2 with single-atom Fe implanting and accompanying Bi decorating on surface is proposed to boost the performance. The single-atom Fe implantation decreases the value of surface work function, allowing the fast transition of photon-generated electrons from the surface of catalyst to CO 2 molecule. In situ Fourier transform infrared (FT-IR) spectra, CO 2 adsorption measurements, density functional theory (DFT) calculations, and efficient CO 2 activation are realized on as-established singleatom catalyst. An exceptional yield of CO (23.77 μmol g −1 h −1 ) and CH 4 production (4.98 μmol g −1 h −1 ) is acquired over optimized Bi 4 O 5 I 2 −Fe30 with 1.09 wt % of singleatom Fe, superior to Bi 4 O 5 I 2 , and most other reported photocatalysts. The work paves a insight into rational design of photocatalysts toward simultaneously facilitating carrier separation and CO 2 activation from the angle of atom single metal.

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