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This article is focused on the formation of hydride blisters in zirconium alloys an experimental and theoritical standpoint, and their characterization in terms of morphology, hydrides crystallographic phases, hardness and hydrogen concentration. An experimental setup was developed to grow hydride blisters on pre-hydrided Zircaloy-4 cladding tubes by thermo-diffusion. The thermal conditions were optimized based on thermo-diffusion calculations, that take into account the hysteresis in the hydrogen solubility limit, to obtain a high blister growth rate. Micro X-Ray Diffraction (XRD), nano-hardness and Elastic Recoil Detection Analysis (ERDA) showed that the blisters contain a hydrogen gradient, with pure δ-hydride phase close to the external surface over one third of the blister depth. thermo-diffusion * Tel.: +33 1 69 08 39 43; e-mail: arthur.hellouin-de-menibus@cea.fr 1 calculations showed these half thickness blisters should grow in only a few days in PWR conditions. Eventually, the Diffusion Equilibrium Threshold (DET) was defined as a criterion that limits the blister growth, and emphasizes that the hysteresis in the hydrogen solubility limit in zirconium must be taken into account to model hydrogen thermo-diffusion in zirconium alloys.

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test, which induces a near uniaxial loading, were proposed and developed to reach higher biaxiality ratios (ratio between mechanical quantities in axial and in circumferential direction). The first optimization, named HB-EDC for High-Biaxiality EDC, allowed to reach transverse plane strain conditions. The second optimization, named VHB-EDC for Very High Biaxiality EDC, was designed to reach higher loading biaxiality ratios. These optimized EDC tests were performed * Tel.: +33 1 69 08 39 43; e-mail: arthur.hellouin-de-menibus@cea.fr 1 at 25 • C, 350 • C and 480 • C on unirradiated hydrided Cold Worked Stress Relieved (CWSR) Zircaloy-4 samples. First, samples unhydrided or uniformly hydrided up to 1130 wppm were tested. Secondly, samples hydrided at 310 wppm with a hydride blister were tested. A large ductility reduction is induced by the increase in biaxiality level in absence of a hydride blister or with small blisters (<50 µm deep). The fracture strain decreases quickly with the blister depth at 25 • C, but more progressively at higher temperature. An equation that quantifies the fracture strain reduction with the blister depth is proposed. Eventually, one of the tests developed in the present study, the HB-EDC test, was proven to be a good compromise between the test complexity and the stress state reached. It is a good candidate to characterize the mechanical behaviour of irradiated cladding.

The influence of hydride blister on cold worked stress relieved Zircaloy-4 cladding tubes fracture toughness at room temperature was studied using hoop tensile tests and plane strain tensile tests. The experimental macroscopic fracture stress and strain values and an elastic-plastic finite element analysis of the mechanical tests with the CAST3M code were used to calculate the J-integral and estimate the fracture toughness for several blister depths from 120 to 240 μm.

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International audienceThis study is focused on the hydrogen-induced dimensional change or "growth" of zirconium alloys. Dilatometric experiments were performed on samples taken from a unirradiated Zircaloy-4 (Zy-4) fuel cladding loaded up to 940 wppm hydrogen. Samples were taken in the axial direction of the tube or at 45° to the axial and transverse directions. The results indicate that hydrogen-induced expansion is anisotropic. Theoretical expansion calculations were carried out considering the partition of hydrogen in solid solution and hydrides together with the material crystallographic texture. Hydride-induced expansion was calculated using two different assumptions reported in the literature, namely "Pure Lattice Transformation Strains" (PLTS) and "Pure Shear Transformation Strains" (PSTS). Calculations based on the PSTS hypothesis satisfactorily predicted the anisotropy observed in the dilatometric curve. Under this assumption, the contribution of hydrides to the axial growth of high-burnup Zy-4 cladding is limited to 12%. This study shows it is important to consider the respective contribution of hydrogen in both states, together with the material crystallographic texture, to understand the dilatometric behavior of hydrided zirconium alloys

a b s t r a c tThis study is focused on the impact of rapid Reactivity Initiated Accident (RIA) representative strain rates (about 1 s À1 NEA, 2010) on the behavior and fracture of unirradiated cold work stress relieved Zircaloy-4 cladding tubes. Uniaxial ring tests (HT) and plane strain ring tensile tests (PST) were performed in the 0.1-10 s À1 strain rate range, at 25°C. The local temperature increase due to plastic dissipation was measured with a high-speed infrared camera.Limited temperature increases were measured at 0.1 s À1 strain rate. Limited but not strongly localized temperature increases were measured at 1 s À1 . Large temperature increase were measured at 5 and 10 s À1 (142°C at 5 s À1 strain rate in HT tests). The local temperature increase induced heterogeneous temperature fields, which enhanced strain localization and resulted in a reduction of the plastic elongation at fracture.