The construction of a high efficiency and stable catalyst for use in electrochemical hydrogen generation has great significance for renewable energy technologies. Herein, we show for the first time that Ru decorated with NiCoP is an excellent hydrogen evolving catalyst in both acidic and alkaline conditions, close in performance to that of Pt/C.

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Enhanced electrocatalytic HER is demonstrated by constructing atomically dispersed MoRu pairs with abundant dangling unsaturated O and Ru vacancies on rGO-MoO3−x using an in situ versatile electrostatic assembly strategy.

The eCO2RR activity is correlated to the internal structural character of the catalyst. We employ two types of structural models of porphyrin-based MOFs of PCN-222(Cu) and PCN-224(Cu), featured with the...

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