Existing ionic artificial muscles still require a technology breakthrough for much faster response speed, higher bending strain, and longer durability. Here, we report an MXene artificial muscle based on ionically cross-linked Ti3C2Tx with poly(3,4 ethylenedioxythiophene)-poly(styrenesulfonate), showing ultrafast rise time of within 1 s in DC responses, extremely large bending strain up to 1.37% in very low input voltage regime (0.1 to 1 V), long-term cyclic stability of 97% up to 18,000 cycles, markedly reduced phase delay, and very broad frequency bandwidth up to 20 Hz with good structural reliability without delamination under continuous electrical stimuli. These artificial muscles were successfully applied to make an origami-inspired narcissus flower robot as a wearable brooch and dancing butterflies and leaves on a tree as a kinetic art piece. These successful demonstrations elucidate the wide potential of MXene-based soft actuators for the next-generation soft robotic devices including wearable electronics and kinetic art pieces.
Most materials and devices with structurally switchable color features responsive to external stimuli can actively and flexibly display various colors. However, realizing covert–overt transformation behavior, especially switching between transparent and colored states, is more challenging. A composite laminate of soft poly(dimethylsiloxane) (PDMS) with a rigid SiO2‐nanoparticle (NP) structure pattern is developed as a multidimensional structural color platform. Owing to the similarity in the optical properties of PDMS and SiO2 NPs, this device is fully transparent in the normal state. However, as their mechanical strengths differ considerably, upon compressive loading, a buckling‐type instability arises on the surface of the laminate, leading to the generation of 1D or 2D wrinkled patterns in the form of gratings. Finally, an application of the device in which quick response codes are displayed or hidden as covert–overt convertible colored patterns for optical encryption/decryption, showing their remarkable potential for anticounterfeiting applications, is demonstrated.
The rapid advances in the Internet of things and wearable devices have created a massive platform for sensor systems that detect chemical or biological agents. The accelerated development of these devices in recent years has simultaneously aggravated the power supply problems. Triboelectric nanogenerators (TENGs) represent a thriving renewable energy technology with the potential to revolutionize this field. In this review, the significance of TENG‐based sensor systems in chemical or biological detection from the perspective of the development of power supply for biochemical sensors is discussed. Further, a range of TENGs are classified according to their roles as power supplies and/or self‐powered active sensors. The TENG powered sensor systems are further discussed on the basis of their framework and applications. The working principles and structures of different TENG‐based self‐powered active sensors are presented, along with the classification of the sensors based on these factors. In addition, some representative applications are introduced, and the corresponding challenges are discussed. Finally, some perspectives for the future innovations of TENG‐based sensor systems for chemical/biological detection are discussed.
Growing interest in hybrid organic-inorganic lead halide perovskites has led to the development of various perovskite nanowires (NWs), which have potential use in a wide range of applications, including lasers, photodetectors, and light-emitting diodes (LEDs). However, existing nanofabrication approaches lack the ability to control the number, location, orientation, and properties of perovskite NWs. Their growth mechanism also remains elusive. Here, we demonstrate a micro/nanofluidic fabrication technique (MNFFT) enabling both precise control and in situ monitoring of the growth of perovskite NWs. The initial nucleation point and subsequent growth path of a methylammonium lead iodide-dimethylformamide (MAPbI·DMF) NW array can be guided by a nanochannel. In situ UV-vis absorption spectra are measured in real time, permitting the study of the growth mechanism of the DMF-mediated crystallization of MAPbI. As an example of an application of the MNFFT, we demonstrate a highly sensitive MAPbI-NW-based photodetector on both solid and flexible substrates, showing the potential of the MNFFT for low-cost, large-scale, highly efficient, and flexible optoelectronic applications.
This report presents a simple and inexpensive fabrication approach to a flexible transparent composite film as a "cut-and-paste" surface-enhanced Raman scattering (SERS) substrate for in situ detection of organic pollutants. First, a self-assembled monolayer of Ag-nanocubes (Ag-NCs) is obtained at the air/water interface. Then, the Ag-NC monolayer is retrieved onto a flexible transparent polyethylene (PE) film to achieve an Ag-NC@PE composite film as a flexible SERS substrate. As the Ag-NCs in the monolayer are closely and uniformly packed on the PE film, the Ag-NC@PE composite film shows high SERS-activity with good signal homogeneity and reproducibility. Furthermore, the flexible transparent Ag-NC@PE composite film is "cut into" small pieces and directly "pasted" onto contaminated fruits for in situ SERS detection, as a result 10 nM thiram, 1 μM 4-polychlorinated biphenyl and 10 nM methyl parathion contaminants on oranges are detected, respectively. Therefore the Ag-NC@PE composite film is an inexpensive and effective SERS substrate for rapid in situ detection of organic pollutants in aqueous solutions, on fruits and other solid objects.
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