This study presents an economic and environmentally friendly
method
for the synthesis of microspherical FePO4·2H2O precursors with secondary nanostructures by the electroflocculation
of low-cost iron fillers in a hot solution. The morphology and crystalline
shape of the precursors were adjusted by gradient co-precipitation
of pH conditions. The effect of precursor structure and morphology
on the electrochemical performance of the synthesized LiFePO4/C was investigated. Electrochemical analysis showed that the assembly
of FePO4·2H2O submicron spherical particles
from primary nanoparticles and nanorods resulted in LiFePO4/C exhibiting excellent multiplicity and cycling performance with
first discharge capacities at 0.2C, 1C, 5C, and 10C of 162.8, 134.7,
85.5, and 47.7 mAh·g–1, respectively, and the
capacity of LiFePO4/C was maintained at 85.5% after 300
cycles at 1C. The significant improvement in the electrochemical performance
of LiFePO4/C was attributed to the enhanced Li+ diffusion rate and the crystallinity of LiFePO4/C. Thus,
this work shows a new three-dimensional mesoporous FePO4 synthesized from the iron flake electroflocculation as a precursor
for high-performance LiFePO4/C cathodes for lithium-ion
batteries.
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