Liquid directional self-transport on the functional surface plays an important role in both industrial and academic fields. Inspired by the natural cactus spine and pitcher plant, we have successfully designed a kind of geometry-gradient slippery surface (GGSS) based on aluminum alloy materials which could actively achieve directional self-movement and also antigravity self-movement of various liquid droplets by topography gradient. The mechanism of liquid directional self-transport was theoretically explored through the mechanical analysis of the triple contact line, which was mainly related to the competition between the driven force induced by Laplace pressure and the adhesive force induced by viscous resistance. The adhesive force between the droplet and the surface was quantitatively measured using a homemade experimental apparatus and the results showed that the lateral adhesive force on the GGSS is much smaller than that on the original surface. Additionally, a series of quantitative experiments were conducted to explore the influence of droplet volume and vertex angle on the transport distance and velocity. Finally, we achieved the antigravity self-transport of the droplet on the inclined GGSS to further verify the self-transport ability of the GGSS. We believe that the proposed GGSS with liquid directional self-transport ability in the present work would provide some potential opportunities in modern tribo-systems to optimize the lubricating qualities, especially the lubrication and friction at the extreme contact interface.
Slanted micro-/nano-structures play pivotal roles in a diversity of fields, including water-proof engineering and fogdrop collection. In light of recent advances in fabricating slanted microstructures by using photolithography or reactive ion etching techniques, however, a complex, environmentally unfavorable, and tedious fabrication process makes them far from practical in application. Herein, we present a viable strategy to prepare a slanted shape memory microcone array (SSMMA) by combining the femtosecond laser oblique microfabrication and replica-mold method. Thanks to its fast temperature-responsive feature, SSMMA enables the transition of adhesion forces to effectively control the sliding of droplet on the surface. The underlying principle of the adjustable migration behavior of droplet is that SSMMA switches between the slanted and collapsed states. Moreover, we systematically studied the influence of the microcone spacing/height together with the microcone bending angle on the wetting performance of water droplet. More significantly, the resulted SSMMA analogous to a “machine hand” is experimentally demonstrated to be competent for the grab and transfer of fragile and smooth objects (e.g., coverslip) with a maximum adhesion force of ∼19.404 mN. The current study opens up an avenue for rapidly fabricating functional slanted microstructures for practical usage.
The progress in advanced electronic devices has imposed a great demand for developing flexible electrochemical power devices, which requires a comprehensive understanding of the mechanical-electrochemical coupling behavior of various energy storage materials. Unlike a monotonic capacitance increase of carbon-based double-layer supercapacitors, MXene-based flexible supercapacitors demonstrate a non-monotonic, i.e., "increase-then-decrease" capacitance behavior under the pressure range of 8488 kPa. This non-monotonic capacitance response to pressure is intrinsic to the MXene film as its charge storage is primarily determined by the surface activity, which can be readily affected by pressure-induced dissociation of functionalities, as well as the charge transporting kinetics as limited by the inherent layered structure. The findings described in this study not only expand the knowledge of mechanical-electrochemical coupling to layered MXenes under pressure, but also give a vital design guideline for flexible/stretchable MXene-based energy storage devices or other electronics.
Capillary forces of a shearing liquid bridge can significantly affect the friction and adhesion of interacting surfaces, but the underlying mechanisms remain unclear. We custom built a surface force apparatus (SFA, ±2 μN) equipped with in situ optical microscopy and performed normal and lateral force measurements on a reciprocating water bridge formed between two flat plates. A modified wedge method was developed to correct the unique force measurement errors caused by the changing bridge geometry and position. The results found (1) strong linear relations among the bridge shear displacement, the cosine difference between the left and right contact angles, and the lateral adhesion force and (2) the normal adhesion force increased monotonically up to 13% as the bridge geometry approached its axisymmetric state. Quasi-static force analyses based on a newly developed decahedral model showed good agreement with the experiments and improved accuracy compared with that of cylindrical or rectangular column models previously proposed in the literature. Although limited in certain aspects, this study may (1) prove helpful to the design and analysis of liquid bridge force experiments on platforms similar to the SFA used in this study and (2) help to bridge the gap between friction and liquid bridge physics in the literature.
The 10 000× wear resistance improvement of PTFE by a trace amount of nanofillers has been heavily studied in the past decade and attributed to the moisture-dependent, mechanochemical formation of adherent and carboxylate salt-rich transfer films. However, debates still exist on the role of the fillers in wear reduction. Based on experimental and computational studies of selected PTFE nanocomposites, we proposed that (1) filler-driven polymer defluorination was the first and key step in the mechanochemistry; (2) effective wear-reducing fillers lowered the energy barrier of the defluorination; and (3) filler surface functionality, the amount of chelation products in transfer film, and wear resistance were strongly correlated. This hypothesis was further supported by thermal experiments in this study, which showed that the mechanochemistry and wear resistance were both thermally sensitive.
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