Here SrTaO2N has been found to exhibit photoelectrochemical water splitting, with a theoretical solar‐to‐hydrogen efficiency of 14.4%. Ameliorating the interparticle charge transport by H2 annealing, the solar photocurrent of the SrTaO2N(H) granular film at 1.23 V versus reversible hydrogen electrode (RHE) is increased by ≈250% in comparison with the SrTaO2N film. Using an aberration corrected scanning transmission electron microscope and super‐X energy dispersive spectroscopy, the atomic scale observation has proved a decrease of oxygen concentrations in the surface of SrTaO2N(H) particle, which may allow its electrical conductivity to be increased from 0.77 × 10−6 to 2.65 × 10−6 S cm−1 and therefore the charge separation efficiency has been greatly increased by ≈330%. After being modified by Co–Pi water oxidation catalyst, the SrTaO2N(H) photoanode shows a solar photocurrent of 1.1 mA cm−2 and an incident photo‐to‐current efficiency value of ≈20% at 400–460 nm and 1.23 V versus RHE, which suggests that it is a new promising photoanode material for solar water splitting.
Active, stable, and cost-effective electrocatalysts are attractive alternatives to the noble metal oxides that have been used in water splitting. The direct nucleation and growth of electrochemically active LDH materials on chemically modified MWCNTs exhibit considerable electrocatalytic activity toward oxygen evolution from water oxidation. CoMn-based and NiMn-based hybrids were synthesized using a facile chemical bath deposition method and the as-synthesized materials exhibited three-dimensional hierarchical configurations with tunable Co/Mn and Ni/Mn ratio. Benefiting from enhanced electrical conductivity with MWCNT backbones and LDH lamellar structure, the Co5Mn-LDH/MWCNT and Ni5Mn-LDH/MWCNT could generated a current density of 10 mA cm(-2) at overpotentials of ∼300 and ∼350 mV, respectively, in 1 M KOH. In addition, the materials also exhibited outstanding long-term electrocatalytic stability.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.