Organic-inorganic heterostructures (OIHs) are an emerging topic that has attracted great research enthusiasm due to their unique features for electronic and optoelectronic applications. Although OIHs constructed with topological insulators and...

Due to the wide spectral absorption and ultrafast electron dynamical response under optical excitation, topological insulator (TI) was proposed to have appealing application in next-generation photonic and optoelectronic devices. Whereas, the bandgap-free speciality of Dirac surface states usually leads to a quick relaxation of photoexcited carriers, making the transient excitons difficult to manipulate in isolated TIs. Growth of TI Bi2Te3/Ge heterostructures can promote the specific lifetime and quantity of long-lived excitons, offering the possibility of designing original near-infrared optoelectronic devices, however, the construction of TI Bi2Te3/Ge heterostructures has yet to be investigated. Herein, the high-quality Bi2Te3/Ge heterojunction with clear interface was prepared by PVD strategy. A significant photoluminescence quenching behaviour was observed by experiments, which was attributed to the spontaneous excitation transfer of electrons at heterointerface via theoretical analysis. Then, a self-powered heterostructure photodetector was fabricated, which demonstrated a maximal detectivity of 1.3×1011 Jones, an optical responsivity of 0.97AW-1, and ultrafast photoresponse speed (12.1 μs) under 1064 nm light illumination. This study offers a fundamental understanding of the spontaneous interfacial exciton transfer of TI-based heterostructures, and the as-fabricated photodetectors with excellent performance provided an important step to meet the increasing demand for novel optoelectronic applications in the future.

Organic/inorganic hybrid van der Waals heterostructure with an atomically abrupt interface has attracted great research interests within the field of multifunctional electronic and optoelectronic devices. The integration of organic rubrene films with inorganic Si semiconductors can avoid the atomic mutual-diffusion at the interface, and provide the possibility of forming two-dimensional van der Waals heterojunction accompanied with the type-II energy band alignment, due to the transfer behaviors of majority carriers at the interface. In this study, the high-quality rubrene/Si van der Waals heterostructure with an electronically abrupt junction was prepared, and a self-powered photodetector was then constructed based on this hybrid heterojunction. The photodetector demonstrated an excellent switching response to the 1064 nm monochromatic light with large on/off current ratio of 7.0 × 103, the maximum photocurrent of 14.62 mA, the maximum responsivity of 2.07 A/W, the maximum detectivity of 2.9 × 1011 Jones, and a fast response time of 13.0 μs. This study offers important guidance for preparing high-quality rubrene/Si hybrid van der Waals heterostructure with desirable band alignment, and the designed heterojunction photodetector has an important application prospect in the field of multifunctional optoelectronics.

Pd/Co2MnSi (CMS)/NiFe2O4 (NFO)/Pd multilayers were fabricated on F-mica substrate by magnetron sputtering. The best PMA performance of the multilayer structure Pd(3 nm)/CMS(5 nm)/NFO(0.8 nm)/Pd(3 nm) was obtained by adjusting the thickness of the CMS and NFO layers. F-mica substrate has a flatter surface than glass and Si/SiO2 substrate. The magnetic anisotropy energy density (K eff) of the sample deposited on F-mica substrates is 0.6711 Merg/cm3 (1 erg=10−7 J), which is about 30% higher than that of the multilayer films deposited on glass (0.475 Merg/cm3) and Si/SiO2 (0.511 Merg/cm3) substrates, and the R Hall and H C are also significantly increased. In this study, the NFO layer prepared by sputtering in the high purity Ar environment was exposed to the high purity O2 atmosphere for 5 min, which can effectively eliminate the oxygen loss and oxygen vacancy in NFO, ensuring enough Co–O orbital hybridization at the interface of CMS/NFO, and thus effectively improve the sample PMA.