Corrosion at the taper/trunnion interface of total hip replacement (THR) often results in severe complications. However, the underlying mechanisms of biotribocorrosion at the taper/trunnion interface during the long-term walking gait cycles remain to be fully understood. In this study, a hip joint simulator was therefore instrumented with an electrochemical cell for in-situ monitoring of the tribocorrosion evolution in a metal-on-polyethylene (MoP) THR during a typical long-term walking gait. In addition, the biotribocorrosion mechanism was investigated via surface and chemical characterizations. The experimental results confirmed that the taper/trunnion interface dominated the contemporary MoP hip joint corrosion. Three cyclic variations in the open circuit potential (OCP) were observed throughout the long-term electrochemical measurements, attributed to the formation and disruption of the adsorbed protein layer. The corrosion exhibited an initial increase at each period, peaking at approximately 0.125 million cycles, followed by a subsequent gradual reduction. Surface and chemical analyses revealed the formation of a tribochemical reaction layer (tribolayer) on the worn surface of the taper/trunnion interface. The surface/chemical characterizations and the electrochemical measurements indicated that the adhesion force of the adsorbed protein layer was weaker than that of the tribolayer. In contrast, the opposite was true for the corrosion resistance. Based on the observations from this study, the tribocorrosion mechanism of the taper/trunnion interface under the long-term walking gait cycles is deduced.
Purpose This study aims to systematically investigate the tribological behaviors of metal and polyethylene using lubricants composed of four synovial fluid (SF) components. In addition, the changes in protein conformation during wear were analyzed to establish the correlation between protein conformation and tribological properties. Design/methodology/approach A pin-on-disk tester with multidirectional sliding motion was used for tribological properties observation between metal and polyethylene pairs. Simulated SFs with four main constituents were used as the testing lubricants. Differential scanning calorimetry and Raman were used to characterize the changes in protein conformation during wear. Findings The coupling of lipids and hyaluronic acid further suppressed protein denaturation. The protein structures of the adsorption film and the ensnared protein chains in the friction zone were maintained to a certain extent, thus improving the friction and wear of polyethylene. Originality/value These findings established the correlation between protein conformation and friction and wear, promoting the understanding of the lubrication mechanism of artificial joints.
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