Despite the high theoretical capacity of the sodium-sulfur battery, its application is seriously restrained by the challenges due to its low sulfur electroactivity and accelerated shuttle effect, which lead to low accessible capacity and fast decay. Herein, an elaborate carbon framework, interconnected mesoporous hollow carbon nanospheres, is reported as an effective sulfur host to achieve excellent electrochemical performance. Based on in situ synchrotron X-ray diffraction, the mechanism of the room temperature Na/S battery is proposed to be reversible reactions between S and NaS, corresponding to a theoretical capacity of 418 mAh g. The cell is capable of achieving high capacity retention of ∼88.8% over 200 cycles, and superior rate capability with reversible capacity of ∼390 and 127 mAh g at 0.1 and 5 A g, respectively.
Room‐temperature sodium–sulfur (RT Na–S) batteries have attracted extensive attention because of their low cost and high specific energy. RT Na–S batteries, however, usually suffer from sluggish reaction kinetics, low reversible capacity, and short lifespans. Herein, it is shown that chain‐mail catalysts, consisting of porous nitrogen doped carbon nanofibers (PCNFs) encapsulating Co nanoparticles (Co@PCNFs), can activate sulfur via electron engineering. The chain‐mail catalysts Co@PCNFs with a micrograde hierarchical structure as a freestanding sulfur cathode (Co@PCNFs/S) can provide space for high mass loading of sulfur and polysulfides. The electrons can rapidly transfer from chain‐mail catalysts to sulfur and polysulfides during discharge–charge processes, therefore boosting its conversion kinetics. As a result, this freestanding Co@PCNFs/S cathode achieves a high sulfur loading of 2.1 ± 0.2 mg cm−2, delivering a high reversible capacity of 398 mA h g−1 at 0.5 C (1 C = 1675 mA g−1) over 600 cycles and superior rate capability of an average capacity of 240 mA h g−1 at 5 C. Experimental results, combined with density functional theory calculations, demonstrate that the Co@PCNFs/S can efficiently improve the conversion kinetics between the polysulfides and Na2S via transferring electrons from Co to them, thereby realizing efficient sulfur redox reactions.
Large amount of human motion capture data have been increasingly recorded and used in animation and gaming applications. Efficient retrieval of logically similar motions from a large data repository thereby serves as a fundamental basis for these motion data based applications. In this paper we present a perceptually consistent, example-based human motion retrieval approach that is capable of efficiently searching for and ranking similar motion sequences given a query motion input. Our method employs a motion pattern discovery and matching scheme that breaks human motions into a part-based, hierarchical motion representation. Building upon this representation, a fast string match algorithm is used for efficient runtime motion query processing. Finally, we conducted comparative user studies to evaluate the accuracy and perceptualconsistency of our approach by comparing it with the state of the art example-based human motion search algorithms.
In this work, a novel scheme is proposed to compress human motion capture data based on hierarchical structure construction and motion pattern indexing. For a given sequence of 3D motion capture data of human body, the 3D markers are first organized into a hierarchy where each node corresponds to a meaningful part of the human body. Then, the motion sequence corresponding to each body part is coded separately. Based on the observation that there is a high degree of spatial and temporal correlation among the 3D marker positions, we strive to identify motion patterns that form a database for each meaningful body part. Thereafter, a sequence of motion capture data can be efficiently represented as a series of motion pattern indices. As a result, higher compression ratio has been achieved when compared with the prior art, especially for long sequences of motion capture data with repetitive motion styles. Another distinction of this work is that it provides means for flexible and intuitive global and local distortion controls.
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