A bifunctional conjugated organic molecule 4-(aminomethyl) benzoic acid hydroiodide (AB) is designed and employed as an organic cation in organic-inorganic halide perovskite materials. Compared with the monofunctional cation benzylamine hydroiodide (BA) and the nonconjugated bifunctional organic molecule 5-ammonium valeric acid, devices based on AB-MAPbI show a good stability and a superior power conversion efficiency of 15.6% with a short-circuit current of 23.4 mA cm , an open-circuit voltage of 0.94 V, and a fill factor of 0.71. The bifunctional conjugated cation not only benefits the growth of perovskite crystals in the mesoporous network, but also facilitates the charge transport. This investigation helps explore new approaches to rational design of novel organic cations for perovskite materials.
Perovskite solar cells (PSCs) usually suffer an anomalous hysteresis in current-voltage measurements that leads to an inaccurate estimation of the device efficiency. Although ion migration, charge trapping/detrapping and accumulation have been proposed as a basis for the hysteresis, the origin of hysteresis has not been apparently unraveled. Herein we reported a tunable hysteresis effect based uniquely on open-circuit voltage variations in printable mesoscopic PSCs with a simplified triple-layer TiO2/ZrO2/Carbon architecture. The electrons are collected by the compact TiO2/mesoporous TiO2 (cTiO2/mp-TiO2) bilayer, and the holes are collected by the carbon layer. By adjusting the spray deposition cycles for the cTiO2 layer, we achieved hysteresis-normal, hysteresis-free, and hysteresis-inverted PSCs. Such unique trends of tunable hysteresis are analysed by considering the polarization of the TiO2/perovskite interface, which can accumulate positive charges reversibly. Successfully tuning the hysteresis effect clarifies the critical importance of the c-TiO2/perovskite interface in controlling the hysteretic trends observed, providing important insights towards the understanding of this rapidly developing photovoltaic technology.
Microsoft Kinect camera and its skeletal tracking capabilities have been embraced by many researchers and commercial developers in various applications of real-time human movement analysis. In this paper, we evaluate the accuracy of the human kinematic motion data in the first and second generation of the Kinect system, and compare the results with an optical motion capture system. We collected motion data in 12 exercises for 10 different subjects and from three different viewpoints. We report on the accuracy of the joint localization and bone length estimation of Kinect skeletons in comparison to the motion capture. We also analyze the distribution of the joint localization offsets by fitting a mixture of Gaussian and uniform distribution models to determine the outliers in the Kinect motion data. Our analysis shows that overall Kinect 2 has more robust and more accurate tracking of human pose as compared to Kinect 1.
The present study developed the malevolent creativity behavior scale (MCBS), which contains 13 items and was designed to measure individuals’ malevolent creativity through the behavior of daily lives. A total of 958 participants from different regions of China completed the MCBS in an online fashion. Cronbach’s α coefficient, using the 908 MCBSs with entirely complete data, indicated that the MCBS had satisfactory reliability. Exploratory factor analysis (EFA) and confirmatory factor analysis (CFA) revealed that the MCBS had 3 dimensions: hurting people, lying, and playing tricks. MCBS scores were positively correlated with individuals’ aggression, openness, extraversion, and scores on the Runco Ideational Behavior Scale (RIBS). MCBS scores also predicted individuals’ malevolent creativity performances when solving realistic, open-ended problems. The MCBS has a simple response medium and scoring procedure. This, along with the adequate psychometric properties uncovered here, indicates that it is a useful tool for research on malevolent creativity. Given that the MCBS contains a relatively small number of categories and items, further research could expand the categories of items and develop and test more items. Moreover, it would be useful to test MCBS’s reliability and validity with other criteria. Perhaps future research could obtain actual MC data from criminal or other unambiguously malevolent samples.
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In this study, we analyzed the clinical significance of ferroptosis-related genes (FRGs) in 32 cancer types in the GSCA database. We detected a 2-82% mutation rate among 36 FRGs. In clear cell renal cell carcinoma (ccRCC; n=539) tissues from the The Cancer Genome Atlas database, 30 of 36 FRGs were differentially expressed (up- or down-regulated) compared to normal kidney tissues (n=72). Consensus clustering analysis identified two clusters of FRGs based on similar co-expression in ccRCC tissues. We then used LASSO regression analysis to build a new survival model based on five risk-related FRGs ( CARS, NCOA4, FANCD2, HMGCR, and SLC7A11 ). Receiver operating characteristic curve analysis confirmed good prognostic performance of the new survival model with an area under the curve of 0.73. High FANCD2, CARS, and SLC7A11 expression and low HMGCR and NCOA4 expression were associated with high-risk ccRCC patients. Multivariate analysis showed that risk score, age, stage, and grade were independent risk factors associated with prognosis in ccRCC. These findings demonstrate that this five risk-related FRG-based survival model accurately predicts prognosis in ccRCC patients, and suggest FRGs are potential prognostic biomarkers and therapeutic targets in several cancer types.
Controlling the crystallization of organic–inorganic hybrid perovskite is of vital importance to achieve high performing perovskite solar cells. The growth mechanism of perovskites has been intensively studied in devices with planar structures and traditional structures. However, for the printable mesoscopic perovskite solar cells, it is difficult to study the crystallization mechanism of perovskite owing to the complicated mesoporous structure. Here, a solvent evaporation controlled crystallization method to achieve ideal crystallization in the mesoscopic structure is provided. Combining results of scanning electron microscope and X‐ray diffraction, it is found that adjusting the evaporation rate of solvent can control the crystallization rate of perovskite and a model for the crystallization process during annealing in mesoporous structures is proposed. Finally, a homogeneous pore filling in the mesoscopic structure without any additives is successfully achieved and a stabilized power conversion efficiency of 16.26% using ternary‐cation perovskite absorber is realized. The findings will provide better understanding of perovskite crystallization in printable mesoscopic perovskite solar cells and pave the way for the commercialization of perovskite solar cells.
Solution-processable organic–inorganic perovskite solar cells have attracted much attention in the past few years. Energy level alignment is of great importance for improving the performance of perovskite solar cells because it strongly influences charge separation and recombination. In this report, we introduce three amide additives, namely, formamide, acetamide, and urea, into the MAPbI3 perovskite by mixing them directly in perovskite precursor solutions. The Fermi level of MAPbI3 shifts from −4.36 eV to −4.63, −4.65, and −4.61 eV, respectively, upon addition of these additives. The charge transfer between perovskite and mp-TiO2 is found to be promoted as determined via TRPL spectra, and recombination in the perovskite is suppressed. As a result, the built-in electric field (V bi) of the printable, hole-conductor-free mesoscopic perovskite solar cells based on these perovskites with amide additives is enhanced and a peak power conversion efficiency of 15.57% is obtained.
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