Electro-Fenton is a promising advanced oxidation process for water treatment consisting a series redox reactions. Here, we design and examine an electrochemical filter for sequential electro-Fenton reactions to optimize the treatment process. The carbon nanotube (CNT) membrane stack (thickness ∼ 200 μm) used here consisted of 1) a CNT network cathode for O2 reduction to H2O2, 2) a CNT-COOFe(2+) cathode to chemical reduction H2O2 to (•)OH and HO(-) and to regenerate Fe(2+) in situ, 3) a porous PVDF or PTFE insulating separator, and 4) a CNT filter anode for remaining intermediate oxidation intermediates. The sequential electro-Fenton was compared to individual electrochemical and Fenton process using oxalate, a persistent organic, as a target molecule. Synergism is observed during the sequential electro-Fenton process. For example, when [DO]in = 38 ± 1 mg L(-1), J = 1.6 mL min(-1), neutral pH, and Ecell = 2.89 V, the sequential electro-Fenton oxidation rate was 206.8 ± 6.3 mgC m(-2) h(-1), which is 4-fold greater than the sum of the individual electrochemistry (16.4 ± 3.2 mgC m(-2) h(-1)) and Fenton (33.3 ± 1.3 mgC m(-2) h(-1)) reaction fluxes, and the energy consumption was 45.8 kWh kgTOC(-1). The sequential electro-Fenton was also challenged with the refractory trifluoroacetic acid (TFA) and trichloroacetic acid (TCA), and they can be transferred at a removal rate of 11.3 ± 1.2 and 21.8 ± 1.9 mmol m(-2) h(-1), respectively, with different transformation mechanisms.
Background:
To describe the characteristics of clinical manifestations of children with 2019 novel coronavirus (2019-nCoV) infection in Chongqing.
Methods:
All 25 children with laboratory-confirmed 2019-nCoV infection by real-time reverse transcription-PCR (RNA-PCR) were admitted from the 4 designated treatment hospitals of 2019-nCoV in Chongqing from January 19 to March 12, 2020. Clinical data and epidemiologic history of these patients were retrospectively collected and analyzed.
Results:
The diagnosis was confirmed through RNA-PCR testing. Among the 25 cases, 14 were males and 11 were females. The median age was 11.0 (6.3–14.5) years (range 0.6–17.0 years). All children were related to a family cluster outbreak, and 7 children (28%) with a travel or residence history in Hubei Province. These patients could be categorized into different clinical types, including 8 (32%) asymptomatic, 4 (16%) very mild cases and 13 (52%) common cases. No severe or critical cases were identified. The most common symptoms were cough (13 cases, 52%) and fever (6 cases, 24%). The duration time of clinical symptoms was 13.0 (8.0–25.0) days. In the 25 cases, on admission, 21 cases (84%) had normal white blood cell counts, while only 2 cases (8%) more than 10 × 109/L and 2 cases (8%) less than 4 × 109/L, respectively; 22 cases(88%) had normal CD4+ T lymphocyte counts, while in the remaining 3 cases(8%) this increased mildly; 23 cases had normal CD8+ T lymphocyte counts, while in the remaining 2 cases (8%) CD8+ T lymphocyte counts were mildly increased as well. All Lymphocyte counts were normal. There were no statistical differences of lab results between the groups of asymptomatic cases, mild cases and common cases. There were only 13 cases with abnormal CT imaging, most of which were located in the subpleural area of the bottom of the lung. All patients were treated with interferon, 6 cases combined with Ribavirin, and 12 cases combined with lopinavir or ritonavir. The days from onset to RNA turning negative was 15.20 ± 6.54 days. There was no significant difference of RNA turning negative between the groups of interferon, interferon plus ribavirin and interferon plus lopinavir or ritonavir treatment. All the cases recovered and were discharged from hospital.
Conclusions:
The morbidity of 2019-nCoV infection in children is lower than in adults and the clinical manifestations and inflammatory biomarkers in children are nonspecific and milder than that in adults. RNA-PCR test is still the most reliable diagnostic method, especially for asymptomatic patients.
Interlaced carbon nanotube electrodes (ICE) were prepared by vacuum filtering a well-dispersed carbon nanotube-Nafion solution through a laser-cut acrylic stencil onto a commercial polyvinylidene fluoride (PVDF) microfiltration (MF) membrane. Dead-end filtration was carried out using 10 and 10 CFU mL Pseudomonas fluorescens to study the effects of the electrochemically active ICE on bacterial density and morphology, as well as to evaluate the bacterial fouling trend and backwash (BW) efficacy, respectively. Finally, a simplified COMSOL model of the ICE electric field was used to help elucidate the antifouling mechanism in solution. At 2 V DC and AC (total cell potential), the average bacterial log removal of the ICE-PVDF increased by ∼1 log compared to the control PVDF (3.5-4 log). Bacterial surface density was affected by the presence and polarity of DC electric potential, being 87-90% lower on the ICE cathode and 59-93% lower on the ICE anode than that on the PVDF after filtration, and BW further reduced the density on the cathode significantly. The optimal operating conditions (2 V AC) reduced the fouling rate by 75% versus the control and achieved up to 96% fouling resistance recovery (FRR) during BW at 8 V AC using 155 mM NaCl. The antifouling performance should mainly be due to electrokinetic effects, and the electric field simulation by COMSOL model suggested electrophoresis and dielectrophoresis as likely mechanisms.
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