Birefringent materials are of great
importance in optical communication
and the laser industry, as they can modulate the polarization of light.
Limited by their transparency range, few birefringent materials, except
α-BaB2O4 (α-BBO), can be practically
used in the deep ultraviolet (UV) region. However, α-BBO suffers
from a phase transition and does not have enough transparency in the
deep UV region. By introducing the relatively small alkali metal Na+ cation and the F– anion to keep the favorable
structural features of α-BBO, we report a new birefringent crystal
Na3Ba2(B3O6)2F (NBBF), which has the desirable optical properties. NBBF not only
maintains the large birefringence (Δn = n
o – n
e =
0.2554–0.0750 from 175 nm to 3.35 μm) and extends its
UV cutoff edge to 175 nm (14 nm shorter than α-BBO) but also
eliminates the phase transition and has the lowest growth temperature
(820 °C) among birefringent materials. These results demonstrate
that NBBF is an attractive candidate for the next generation of deep
UV birefringent materials.
Deep-ultraviolet (DUV) nonlinear-optical (NLO) materials generating coherent DUV light by a direct second-harmonic-generation (SHG) process have long been pursued as industrially useful lasers. For several decades, KBeBOF (KBBF) has been regarded as the best DUV-NLO material; it is characterized by a short DUV phase-matching edge of 161 nm and a large SHG coefficient of 0.47 pm/V. However, it suffers a strong layering tendency, hindering the growth of large crystals for commercial use. Here, we use a computer-aided swarm structure searching technique to design an alternative DUV-NLO material with a new atmospheric-pressure phase BeBOF with a P6̅2 c space group (γ-BBF) that outperforms the DUV-NLO properties of KBBF. The predicted DUV phase-matching edge and SHG coefficient of γ-BBF are 152 nm and 0.70 pm/V, respectively. The structure of γ-BBF reduces the layering tendency compared with KBBF because of the absence of K atoms in the γ-BBF crystal. Our work paves the way for superior DUV-NLO materials that can be grown as large crystals for commercial applications.
Searching for high performance materials for optical communication and laser industry in deep-ultraviolet (DUV) region has been the subject of considerable interest. Such materials by design from scratching on multi-component complex crystal systems are challenging. Here, we predict, through density function calculations and unbiased structure searching techniques, the formation of quaternary NaBeBO3 compounds at ambient pressure. Among the four low-energy phases, the P63/m structure exhibits a DUV cutoff edge of 20 nm shorter than α-BaB2O4 (189 nm) – the best-known DUV birefringent material. While the P-6 structure exhibits one time second-harmonic generation efficiency of KH2PO4 and possesses excellent crystal growth habit without showing any layer habit as observed in the only available DUV nonlinear optical material KBe2BO3F2, whose layer habit limits its wide industrial applications. These NaBeBO3 structures are promising candidates for the next generation of DUV optical materials, and the structure prediction technique will shed light on future optical materials design.
Prediction of the birefringence values of borate is very essential for developing new optical materials in UV range. In this paper, the birefringence values of five lead borates, Pb
Infrared nonlinear optical (IR NLO) crystals are the major materials to widen the output range of solid-state lasers to mid- or far-infrared regions. The IR NLO crystals used in the middle IR region are still inadequate for high-power laser applications because of deleterious thermal effects (lensing and expansion), low laser-induced damage threshold, and two-photon absorption. Herein, the unbiased global minimum search method was used for the first time to search for IR NLO optical materials and ultimately found a new IR NLO material NaGaS. It meets the stringent demands for IR NLO materials pumped by high-power laser with the highest thermal conductivity among common IR NLO materials able to avoid two-photon absorption, a classic nonlinear coefficient, and wide infrared transparency.
Rationally designing new inorganic materials with specific functional properties is a fascinating challenge. This is particularly true with the nonlinear optical (NLO) crystals which can expand the spectral ranges of...
By incorporation of the largest-electronegativity F atoms into borate, two novel halogen-containing borates, Li6RbB2O6F and K3B3O3F6, have been synthesized. Interestingly, Li6RbB2O6F is the first borate fluoride in alkali-metal borate. Meanwhile, K3B3O3F6 appears to be the first confirmed alkali-metal fluoroborate crystal grown by a high-temperature solution in air.
Birefringent crystals can create and control polarized light, which has crucial applications in optical communication, polarimetry, and scientific instrumentation. For most of birefringence phenomenon in borate crystals, optic anisotropy mainly...
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.