By developing our previous method [Phys. Rev. A 46, 2337(1992; J. Chem. Phys. 98, 543 (1993)],we show how to calculate Kohn-Sham kinetic energies, orbitals, orbital energies, and exchange-correlation potentials, starting from accurate ground-state electron densities. In addition, given correct total energies, we also show how to obtain exchange-correlation energies. The scheme used is based on the Levy constrained-search method for determining the Kohn-Sham kinetic energy. In our preferred implementation, the total electron-electron repulsion is written as a Fermi-Amaldi term plus the rest, thereby assuring the correct long-range behavior of the exchange-correlation potential. Results are given for He, Be, Ne, and Ar. It is demonstrated that the exact exchange-correlation functional cannot be local.PACS number(sj: 31.20.Sy

Single image rain removal is a typical inverse problem in computer vision. The deep learning technique has been verified to be effective for this task and achieved state-of-theart performance. However, previous deep learning methods need to pre-collect a large set of image pairs with/without synthesized rain for training, which tends to make the neural network be biased toward learning the specific patterns of the synthesized rain, while be less able to generalize to real test samples whose rain types differ from those in the training data. To this issue, this paper firstly proposes a semi-supervised learning paradigm toward this task. Different from traditional deep learning methods which only use supervised image pairs with/without synthesized rain, we further put real rainy images, without need of their clean ones, into the network training process. This is realized by elaborately formulating the residual between an input rainy image and its expected network output (clear image without rain) as a specific parametrized rain streaks distribution. The network is therefore trained to adapt real unsupervised diverse rain types through transferring from the supervised synthesized rain, and thus both the short-of-training-sample and bias-to-supervised-sample issues can be evidently alleviated. Experiments on synthetic and real data verify the superiority of our model compared to the state-of-the-arts.

Hyperspectral images (HSIs) are often corrupted by a mixture of several types of noise during the acquisition process, e.g., Gaussian noise, impulse noise, dead lines, stripes, and many others. Such complex noise could degrade the quality of the acquired HSIs, limiting the precision of the subsequent processing. In this paper, we present a novel tensor-based HSI restoration approach by fully identifying the intrinsic structures of the clean HSI part and the mixed noise part respectively. Specifically, for the clean HSI part, we use tensor Tucker decomposition to describe the global correlation among all bands, and an anisotropic spatial-spectral total variation (SSTV) regularization to characterize the piecewise smooth structure in both spatial and spectral domains. For the mixed noise part, we adopt the 1 norm regularization to detect the sparse noise, including stripes, impulse noise, and dead pixels. Despite that TV regulariztion has the ability of removing Gaussian noise, the Frobenius norm term is further used to model heavy Gaussian noise for some real-world scenarios. Then, we develop an efficient algorithm for solving the resulting optimization problem by using the augmented Lagrange multiplier (ALM) method. Finally, extensive experiments on simulated and real-world noise HSIs are carried out to demonstrate the superiority of the proposed method over the existing state-of-the-art ones.Index Terms-Hyperspectral image (HSI), mixed noise, low rank tensor decomposition, total variation (TV).

Video rain/snow removal from surveillance videos is an important task in the computer vision community since rain/snow existed in videos can severely degenerate the performance of many surveillance system. Various methods have been investigated extensively, but most only consider consistent rain/snow under stable background scenes. Rain/snow captured from practical surveillance camera, however, is always highly dynamic in time with the background scene transformed occasionally. To this issue, this paper proposes a novel rain/snow removal approach, which fully considers dynamic statistics of both rain/snow and background scenes taken from a video sequence. Specifically, the rain/snow is encoded as an online multi-scale convolutional sparse coding (OMS-CSC) model, which not only finely delivers the sparse scattering and multi-scale shapes of real rain/snow, but also well encodes their temporally dynamic configurations by real-time ameliorated parameters in the model. Furthermore, a transformation operator imposed on the background scenes is further embedded into the proposed model, which finely conveys the dynamic background transformations, such as rotations, scalings and distortions, inevitably existed in a real video sequence. The approach so constructed can naturally better adapt to the dynamic rain/snow as well as background changes, and also suitable to deal with the streaming video attributed its online learning mode. The proposed model is formulated in a concise maximum a posterior (MAP) framework and is readily solved by the ADMM algorithm. Compared with the state-of-the-art online and offline video rain/snow removal methods, the proposed method achieves better performance on synthetic and real videos datasets both visually and quantitatively. Specifically, our method can be implemented in relatively high efficiency, showing its potential to real-time video rain/snow removal.Index Terms-multi-scale, convolutional sparse coding, rain/snow removal, online learning, alignment method.