The main objective of this research is the study of the drying kinetics and thermodynamic properties of kelp using heat pump drying technology. The effects of the independent variables of temperature (20–50 °C), air velocity (0.3–1.3 m/s), humidity (20–50%), and thickness (0.8–4.2 mm) on the drying time, moisture uniformity, effective moisture diffusivity (Deff), activation energy (Ea), enthalpy (ΔH), entropy (ΔS), and Gibbs free energy (ΔG) were investigated. The results show that the Page model was effective in describing the moisture content change of kelp during heat pump drying. The Deff varied from 1.00 × 10−11 to 13.00 × 10−11 m2/s and the temperature, air velocity, humidity, and thickness had significant effects on drying time and moisture uniformity. Higher temperature and air velocity with proper humidity shortened the drying time and lessened the influence of thickness on moisture uniformity. The Ea (16.38–26.66 kJ/mol) and ΔH (13.69–24.22 kJ/mol) were significantly increased by thickness. When the temperature was 40 °C, air velocity 1.3 m/s, and air humidity 40%, the moisture content was reduced to 18% in 5 h, with a homogeneous moisture content. This study clarifies the regularity of moisture change inside kelp and provides a theoretical reference for the development of macroalgae drying technology.
In order to solve a series of problems with kelp drying including long drying time, high energy consumption, low drying efficiency, and poor quality of dried kelp, this work proposes the design of a novel greenhouse double-evaporator solar-assisted heat pump drying system. Experiments on kelp solar-assisted heat pump drying (S−HP) and heat pump drying (HP) under the condition of irradiance of 100−700 W/m2 and a temperature of 30, 40, or 50 °C were conducted and their results were compared in terms of system performance, drying kinetics, and quality impact. The drying time was reduced with increasing irradiance or temperature. The coefficient of performance (COP) and specific moisture extraction rate (SMER) of S−HP were 3.590−6.810, and 1.660−3.725 kg/kW·h, respectively, roughly double those of HP when the temperatures are identical. The Deff of S-HP and HP were 5.431 × 10−11~11.316 × 10−11 m2/s, and 1.037 × 10−11~1.432 × 10−11 m2/s, respectively; additionally, solar radiation greatly improves Deff. The Page model almost perfectly described the changes in the moisture ratio of kelp by S−HP and HP with an inaccuracy of less than 5%. When the temperature was 40 °C and the irradiance was above 400 W/m2, the drying time of S−HP was only 3 h, and the dried kelp maintained the green color with a strong flavor and richness in mannitol. Meanwhile, the coefficient of performance was 6.810, the specific moisture extraction rate was 3.725 kg/kWh, and the energy consumption was 45.2%, lower than that of HP. It can be concluded that S−HP is highly efficient and energy-saving for macroalgae drying and can serve as an alternate technique for the drying of other aquatic products.
The main objective is to effectively denature the autolysis enzymes of C. frondosa on the premise of avoiding the quality deterioration caused by overheating. The effects of the different thermal treatments (blanching at 40–80 °C for 45 min, boiling and steaming at 100 °C for 15–120 min) on the cooking yield, moisture content, protein degradation, texture, and enzyme inactivation were studied, and the inner relationship was investigated by multivariate analysis. The autolysis enzymes of C. frondosa were thermally stable and cannot be denatured completely by blanching. Boiling and steaming could efficiently inactivate the enzymes but overheating for 60–120 min reduced the cooking yield and texture quality. Boiling at 100 °C for 45 min was suitable for pre-treatment, with cooking yield of 70.3% and protein content of 78.5%. Steaming at 100 °C for at least 30 min was preferable for long-term storage and instant food, in which the relative activity was only 3.2% with better palatability.
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