Adsorption of asphaltenes at the water-oil interface contributes to the stability of petroleum emulsions by forming a networked film that can hinder drop-drop coalescence. The interfacial microstructure can either be liquid-like or solid-like, depending on: i) initial bulk concentration of asphaltenes, ii) interfacial aging time, and iii) solvent aromaticity. Two techniques: interfacial shear rheology and integrated thin film drainage apparatus provided equivalent interface aging conditions, enabling direct correlation of the interfacial rheology and droplet stability. The shear rheological properties of the asphaltene film were found to be critical to the stability of contacting droplets. With a viscous dominant interfacial microstructure, the coalescence time for two drops in intimate contact was rapid, on the order of seconds. However, as the elastic contribution develops and the film microstructure begins to be dominated by elasticity, the two drops in contact do not coalescence. Such step-change transition in coalescence is thought to be related to the high shear yield stress (~10 4 Pa), which is a function of the film shear yield point and the film thickness (as measured by quartz crystal microbalance), and the increased elastic stiffness of the film that prevents mobility and rupture of the asphaltene film which when in a solid-like state provides an energy barrier for the droplets to coalescence.
Lithiophilic sites with high binding energy to Li have shown the capability to guide uniform Li deposition, however, the irreversible reaction between Li and lithiophilic sites causes a loss of lithiophilicity. Herein, the concept of using reversible lithiophilic sites, such as single‐atoms (SAs) doped graphene, as a host, is systematically inspected in the context of Li metal battery (LMB) performance. Here, it is proposed that the binding energy to Li atoms should be within a certain threshold range, i.e., strong enough to inhibit Li dendrite growth and weak enough to avoid host structure collapse. Six kinds of SAs are utilized; doped 3D graphene, nitrogen‐doped 3D graphene, and pure 3D graphene, whose performance in LMBs are compared with each other. It is discovered that the SA‐Mn doped 3D graphene (SAMn@NG) has the most reversible lithiophilic site, in which adsorption strength with Li is suitable to guide uniform deposition and keep the structure stable. During Li plating/stripping, the changes of the atomic structures in SAMn@NG, such as change of bond length and bond angle around Mn atoms are much smaller than those on SAZr@NG, although its binding energy is higher, enabling a much‐improved battery performance in SAMn@NG. This work provides a new insight to design lithiophilic sites in LMBs.
High
water content is hard to be achieved in conductive hydrogels
because a mass of conductive constituent is needed to form an internal
conductive pathway. Here, we developed anisotropic electrically conductive
hydrogels with high water content based on bacterial cellulose (BC).
Polystyrene sulfonate (PSS) was grafted to the acryloyl chloride-modified
BC to provide a template for the subsequent synthesis of poly(3,4-ethylenedioxythiophene)
(PEDOT). The BC-g-PSS/PEDOT hydrogels obtained were
electrically conductive owing to the immobilization of PEDOT on the
surface of cellulose nanofibers. The hydrogels exhibited an electrical
conductivity of 0.24 S cm–1. Further, they demonstrated
suppleness in compression (compiled to external compression stress
>2.8 MPa and recoverable), inherent high water content (∼95.0
wt %), and anisotropy (anisotropic index of 4.1 in conductivity) from
BC. The incorporation of a thermoresponsive poly(N-isopropylacrylamide) (PNIPAAm) hydrogel into the BC-g-PSS/PEDOT hydrogel demonstrated a uniaxial thermoresponsive actuation
with resistance change. The expected size and resistance change were
only observed in the direction vertical to the cellulose nanofiber
layers. These hydrogels could accommodate further developments in
novel tissue engineering scaffolds, implantable biosensors, and smart
soft electronic devices.
Semi-crystalline shape memory polymers exhibit two-way shape memory effect (2W-SME) under constant stresses through crystallization-induced elongation upon cooling and meltinginduced constriction upon heating. The applied constant stress influenced the prediction and usability of 2W-SME in practical applications without any external force. Here the reversible shape transition in EVA-shaped memory polymer was quantitative analyzed under a suitable temperature range and external stress-free condition. The fraction of reversible strain increased with increasing upper temperature (T high ) within the temperature range and reached the maximum value of 13.62% at 70 °C. However, reversible strain transition was almost lost when T high exceeded 80 °C because of complete melting of crystalline scaffold, known as the latent recrystallization template. The non-isothermal annealing of EVA 2W-SMP under changing circulating temperatures was confirmed. Moreover, the orientation of crystallization was retained at high temperatures. These findings may contribute to design an appropriate shape memory protocol based on application-specific requirements.
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