This paper reports a generic method for preparing re-enforced nanocomposite worm-gels. Aqueous poly(glycerol monomethacrylate)-b-poly(2-hydroxypropyl methacrylate) (PGMA-PHPMA) and methanolic poly(glycerol monomethacrylate)-b-poly(benzyl methacrylate) (PGMA-PBzMA) worm gels were prepared by RAFT-mediated polymerisation-induced self-assembly...

Graphene oxide (GO) containing block copolymer nanocomposite hydrogels formed from poly(glycerol monomethacrylate-block-hydroxypropyl methacrylate) (PGMA-PHPMA) wormlike micelles were prepared by either mixing GO and copolymer at low temperature or via in...

Miniemulsion polymerisation has become widely recognised as a versatile and efficient strategy to prepare well-defined polymer latexes. In this article, we report the synthesis of poly(benzyl methacrylate) (PBzMA) latexes via...

Based on physical modelling, this paper discusses the feasibility of injecting additives to control the conformance of the cyclic steam stimulation (CSS) and steam drive processes in the Biquan 10 Block of the Henan Oil Field. The lab test results show that waterflooding with the addition of a carbamide surfactant can decrease residual oil saturation by 4.7% and that steam drive with the addition of this same surfactant can improve the sweep volume and increase the oil recovery factor by 17.5%. Also, field application results confirmed that injecting this surfactant in the CSS and steam drive processes can increase oil production, lower steam-oil ratio (SOR) and improve the economic benefitssignificantly. Introduction The CSS process has been applied in developing the heavy oil reservoirs in the Henan Oil Field since the late 1980s. It has been clearly demonstrated that with increasing the cycles of steam stimulation, the oil production rate decreases and SOR can rapidly reach the economic limit. For improving the oil production rate and recovery factor, the steam drive process needs to be applied as a subsequent technology. However, the reservoir in the Henan Oil Field is thin and interbedded so it is a challenge to operate the conventional steam drive process. To reduce the steam channeling effect, a number of high temperature resistant plugging surfactants have been tested, but they could not achieve ideal and persistent results(1). This paper discusses the development of a new kind of conformance control agent ? carbamide surfactant. The lab testing results and field applications of the steam drive process with the addition of a carbamide surfactant in Well Group 577, Biqian 10 Block, Henan Oil Field, are described in detail below. Mechanism and Physical Modelling When the carbamide surfactant is injected into the reservoir with steam, carbamide decomposes into CO2 and NH3 under high temperatures. The decomposition can be expressed as follows: Equation (available in full paper) The physical modelling shows that, with increasing temperature and pressure, the carbamide decomposes even faster but its concentration does not affect the decomposition speed. The produced CO2 dissolves in heavy oil and NH3 can react with some acid in the oil. As a result, the heavy oil volume expands and viscosity decreases. At 50 °C, when the oil-carbamide solution (30 wt% carbamide) ratio is 4 to 1, the oil viscosity can be reduced by 73% to 80%. The single tube displacement efficiency test shows that adding carbamide solution (30 wt% carbamide) into hot water will increase the displacing efficiency by 6.5%. Field Application and Discussion Reservoir Geology and Production History Well pattern 577 in the east of Biqian 10 block was selected for the field test. The well pattern is an inverted 9-spot with injector-producer spacing of 70 m and 100 m. The pay zone is the IV-9 layer of the H-3 interval in the Hetaoyuan Formation. The basic reservoir parameters are as follows: