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Lithium metal anodes are critical enablers for high energy density next generation batteries, but they suffer from poor morphology control and parasitic reactions. Recent experiments have shown that an external packing force on Li metal batteries with liquid electrolytes extends their lifetimes by inhibiting the growth of dendritic structures during Li deposition. However, the mechanisms by which pressure affects dendrite formation and growth have not been fully elucidated. For

The “Stribeck curve” is a well-known concept, describing the frictional behavior of a lubricated interface during the transition from boundary and mixed lubrication up to full-film hydrodynamic/elastohydrodynamic lubrication. It can be found in nearly every tribology textbook/handbook and many articles and technical papers. However, the majority of the published Stribeck curves are only conceptual without real data from either experiments or numerical solutions. The limited number of published ones with real data is often incomplete, covering only a portion of the entire transition. This is because generating a complete Stribeck curve requires experimental or numerical results in an extremely wide range of operating conditions, which has been a great challenge. Also, numerically calculating a Stribeck curve requires a unified model with robust algorithms that is capable of handling the entire spectrum of lubrication status. In the present study, numerical solutions in counterformal contacts of rough surfaces are obtained by using the unified deterministic mixed elastohydrodynamic lubrication (EHL) model recently developed. Stribeck curves are plotted in a wide range of speed and lubricant film thickness based on the simulation results with various types of contact geometry using machined rough surfaces of different orientations. Surface flash temperature is also analyzed during the friction calculation considering the mutual dependence between friction and interfacial temperature. Obtained results show that in lubricated concentrated contacts, friction continuously decreases as speed and film thickness increase even in the full-film regime until extremely high speeds are reached. This is mainly due to the reduction of lubricant limiting shear stress caused by flash temperature rise. The results also reveal that contact ellipticity and roughness orientation have limited influence on frictional behaviors, especially in the full-film and boundary lubrication regimes.

The Stribeck curve is an important means to demonstrate the frictional behavior of a lubricated interface during the entire transition from boundary and mixed to full-film lubrication. In the present study, a new test apparatus has been built that can operate under rolling–sliding conditions at a continuously variable speed in an extremely wide range, approximately from 0.00006 to 60 m/s, covering six orders of magnitude. Hence, a complete Stribeck curve can be measured to reveal its basic characteristics for lubricated counterformal contacts. The measured curves are compared with numerical simulation results obtained from an available unified mixed elastohydrodynamic lubrication (EHL) model that is also capable of handling cases during the entire transition. A modified empirical model for the limiting shear stress of lubricant is obtained, and a good agreement between the measured and calculated Stribeck curves is achieved for the tested base oils in all the three lubrication regimes, which thus well validates the simulation methods employed. Both the experimental and numerical results indicate that the Stribeck curves for counterformal contact interfaces behave differently from those for conformal contacts. When the rolling speed increases at a fixed slide-to-roll ratio, the friction continuously decreases even in the full-film lubrication regime due to the reduction of the lubricant limiting shear stress caused mainly by the rise of the surface flash temperature. In addition, the test results indicate that the boundary additives in a commodity lubricant may have considerable influence on the boundary lubrication friction but that on the friction in the mixed and full-film lubrication appears to be limited.

Computational contact mechanics seeks for numerical solutions to contact area, pressure, deformation, and stresses, as well as flash temperature, in response to the interaction of two bodies. The materials of the bodies may be homogeneous or inhomogeneous, isotropic or anisotropic, layered or functionally graded, elastic, elastoplastic, or viscoelastic, and the physical interactions may be subjected to a single field or multiple fields. The contact geometry can be cylindrical, point (circular or elliptical), or nominally flat-to-flat. With reasonable simplifications, the mathematical nature of the relationship between a surface excitation and a body response for an elastic contact problem is either in the form of a convolution or correlation, making it possible to formulate and solve the contact problem by means of an efficient Fourier-transform algorithm. Green's function inside such a convolution or correlation form is the fundamental solution to an elementary problem, and if explicitly available, it can be integrated over a region, or an element, to obtain influence coefficients (ICs). Either the problem itself or Green's functions/ICs can be transformed into a space-related frequency domain, via a Fourier transform algorithm, to formulate a frequency-domain solution for contact problems. This approach converts the original tedious integration operation into multiplication accompanied by Fourier and inverse Fourier transforms, and thus a great computational efficiency is achieved. The conversion between ICs and frequency-response functions facilitate the solutions to problems with no explicit space-domain Green's function. This paper summarizes different algorithms involving the fast Fourier transform (FFT), developed for different contact problems, error control, as well as solutions to the problems involving different contact geometries, different types of materials, and different physical issues. The related works suggest that (i) a proper FFT algorithm should be used for each of the cylindrical, point, and nominally flat-flat contact problems, and then (ii) the FFT-based algorithms are accurate and efficient. In most cases, the ICs from the 0order shape function can be applied to achieve satisfactory accuracy and efficiency if (i) is guaranteed.

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Steady-state mixed hydrodynamic lubrication of rigid journal bearing is investigated by using a finite difference form of the Patir–Cheng average Reynolds equation under the Reynolds boundary condition. Two sets of discretization meshes, i.e., the rectangular and nonorthogonal herringbone meshes, are considered. A virtual-mesh approach is suggested to resolve the problem due to the singularities of pressure derivatives at the turning point of the herringbone mesh. The effectiveness of the new approach is examined by comparing the predicted load with that found in the literature for a smooth-surface case solved in the conventional rectangular mesh. The effects of the skewness angles of symmetric and asymmetric herringbone meshes on the predicted parameters, such as load, friction coefficient, attitude angle, and maximum pressure, are investigated for smooth, rough, and herringbone-grooved bearing surfaces. It is found that the new approach helps to improve the computational accuracy significantly, as demonstrated by comparing the results with and without the treatment of the pressure derivative discontinuity although the latter costs slightly less computational time.

All-solid-state batteries (ASSBs) using an alkali metal anode and a solid-state electrolyte (SE) face several problems due to poor physical and electrical contact. Recent experiments have shown that applying a stack pressure can improve the interface contact and suppress void formation. The mechanical properties of Na metal are different from those of Li metal, leading to differences in the mechanisms of the pressure-dependent interface evolution. Herein, we report a three-dimensional time-dependent model for tracking the evolution of interfaces formed between Na metal and Na-β″-alumina SE. Our results show that Na metal contacts more conformally with the SE, providing a lower interfacial resistance, compared with Li metal, assuming equal resistance due to contamination. The differences due to contact elastoplasticity are larger than the differences in metal creep effects. In fact, we show that increased stack pressure can lead to lower creep because the contact is more conformal at high pressures. Our excellent agreement with recent experiments determines an effective hardness of Na in the Na-SE batteries to be 15 MPa. The results further reveal that the pressure dependence of void suppression is dominated by contact elastoplasticity.