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The change in the core electron ionization potential of CO when complexed to first row transition metals (Cr, Mn and Fe) has been measured directly in the gas phase. For the binary carbonyls shifts of approximately 2.5 eV to lower binding energy are observed. Taking Ni(CO)4 as an example, a number of theoretical methods of calculating such shifts are investigated, but none are found to be satisfactory. Measurements of core level shifts in the molecules LMn(C0)5 are reported and discussed satisfactorily using ab initiu and approximate molecular orbital calculations.

Electron induced Auger electron spectroscopy of solid surfaces has proved a valuable analytical technique over the past ten years. In this paper the state of the technique is reviewed and compared with other methods of Auger spectroscopy, e.g. X-ray induced AES.