In situ SAXS measurements of silica gel formation in the" presence of different cations are presented as a function of reaction time. Conditions used are similar to those applied to prepare catalyst supports. The data can be interpreted in terms of aggregation of elementary silica particles with sizes of approximately 1 nm, thus finally forming a continuous silica gel network. The aggregates are fractal with respect to their masses, in the range 2-10 nm. The dimensionality of the fractals can be determined from the SAXS curves; it increases from 1.8 to 2.5 during gelformation, corresponding with a diffusion limited aggregation process (DLA) of gel formation followed by densification of the silica gel network. The finding that the rate of change in fractal dimensionality does not change as a function of cation, indicates strongly that gelformation is a diffusion limited aggregation process.
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