No abstract

No abstract

No abstract

X-ray diffraction patterns of pure and spent VPO samples.

BACKGROUND: The utilization of biomass and agricultural wastes for production of biofuels is of interest as a research topic, since it could provide a cheaper process due to the wide availability and low cost of raw materials.

No abstract

Designing and developing non-noble metal-based heterogeneous catalysts have a substantial importance in biomass conversion. Meerwein-Ponndorf-Verley (MPV) reaction is a significant pathway for eco-friendly catalytic transfer hydrogenation (CTH) of biomass derived furfural into furfuryl alcohol. In this work, a series of copper-supported hydroxyapatite (HAp) catalysts with different copper loadings (2–20 wt.%) were prepared by a facile impregnation method and tested in the reduction of furfural to furfuryl alcohol using 2-propanol as a hydrogen donor. The structural and chemical properties of the synthesised catalysts were analysed by using various techniques (XRD, N2 sorption, SEM, TEM, UV-DRS, ICP, FTIR, TPR, TPD-CO2 and N2O titration). The effect of copper loading was found to be significant on the total performance of the catalysts. The results demonstrate that 5CuHAp catalyst possess highly dispersed copper particles and high basicity compared to all other catalysts. Overall, 5CuHAp exhibited highest conversion (96%) and selectivity (100%) at 140 °C at 4 h time on stream. The optimised reaction conditions were also determined to gain the high activity.

The valuable products produced from glycerol transformation have become a research route that attracted considerable benefits owing to their huge volumes in recent decades (as a result of biodiesel production as a byproduct) as well as a myriad of chemical and biological techniques for transforming glycerol into high-value compounds, such as fuel additives, biofuels, precursors and other useful chemicals, etc. Biodiesel has presented another challenge in the considerable increase in its byproduct (glycerol). This review provides a recent update on the transformation of glycerol with an exclusive focus on the various catalysts’ performance in designing reaction operation conditions. The different products observed and cataloged in this review involved hydrogen, acetol, acrolein, ethylene glycol, and propylene glycol (1,3-propanediol and 1,2-propanediol) from reforming and dehydration and hydrogenolysis reactions of glycerol conversions. The future prospects and critical challenges are finally presented.