Electrochemical devices such as fuel cells, electrolyzers, lithium-air batteries, and pseudocapacitors are expected to play a major role in energy conversion/storage in the near future. Here, it is demonstrated how desirable bulk metallic glass compositions can be obtained using a combinatorial approach and it is shown that these alloys can serve as a platform technology for a wide variety of electrochemical applications through several surface modification techniques.
The glass forming ability (GFA) of metallic glasses (MGs) is quantified by the critical cooling rate (R
C). Despite its key role in MG research, experimental challenges have limited measured R
C to a minute fraction of known glass formers. We present a combinatorial approach to directly measure R
C for large compositional ranges. This is realized through the use of compositionally-graded alloy libraries, which were photo-thermally heated by scanning laser spike annealing of an absorbing layer, then melted and cooled at various rates. Coupled with X-ray diffraction mapping, GFA is determined from direct R
C measurements. We exemplify this technique for the Au-Cu-Si system, where we identify Au56Cu27Si17 as the alloy with the highest GFA. In general, this method enables measurements of R
C over large compositional areas, which is powerful for materials discovery and, when correlating with chemistry and other properties, for a deeper understanding of MG formation.
By utilizing bulk metallic glasses' (BMGs) unique combination of amorphous structure, material properties, and fabrication opportunities, ultrasmooth and symmetric 3-D metallic glass resonators that are complimentary metal oxide semiconductor (CMOS) post-processing compatible are fabricated. Surface roughness to size ratio fabrication precision in the order of 100 parts per billion is demonstrated with a 3-mm diameter Pt 57.5 Cu 14.7 Ni 5.3 P 22.5 BMG hemispherical shell with a thickness variation <100 nm and a surface roughness of <1 nm R a . The resonator exhibits a resonant frequency of 13.9440 kHz ± 0.1 Hz with 0.035% frequency mismatch between degenerate N = 2 wineglass modes with a quality factor of 6200. This performance was obtained in the asmolded state without any device tuning or trimming. Another resonator with N = 2 resonant modes at 9.393 and 9.401 kHz, and quality factors of 7800 and 6500 was mounted into an integrated electrode system. Electrical readout by capacitive sensing in both time and frequency domains showed a resonance shift to 9.461 and 9.483 kHz, respectively. The quality factor was reduced to 5400 and 5300, respectively. This investigation demonstrates that BMG resonators may serve as a basis for robust microelectromechanical systems resonator devices with increased performance and low-cost fabrication techniques that exploits the atomic structure, unique softening behavior, strength, formability, and toughness of metallic glasses.[2014-0187]
Powder bed fusion (PBF) processing parameters are developed for a FeCrMoBC glass‐forming alloy. Although bulk metallic glass parts are successfully fabricated using additive manufacturing, the porosity is too high for imparting good mechanical properties. The processing is tuned to create a fully‐dense, dendrite‐reinforced metal‐matrix composite with low hardness and high indentation fracture toughness. Microstructures and properties of the printed alloy are compared to bulk amorphous samples made through thermal spray additive manufacturing (TSAM). The work shows that printing glass‐forming alloys can result in tunable properties based on the cooling rate, porosity, and composite microstructures.
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