Conducting polymers are employable as low-voltage actuators, sensors, energy storage and delivery components, structural elements, computational circuitry, memory, and electronic components, making them a versatile choice for creating integrated, multifunctional materials and devices. Here we show one such conducting polymer-based, multifunctional system, derived from the versatility of the conducting polymer polypyrrole. Three functions of polypyrrole (actuation, length sensation, and energy storage) have been individually evaluated and cooperatively combined in the synthesis of a multifunctional, polymeric system that actuates, senses strain deformation, and stores energy. The system operates whereby the strain of a polypyrrole actuator is measured by a polypyrrole length sensor, whilst being powered by an array of polypyrrole supercapacitors. Independently, polypyrrole actuators were evaluated at 250 discrete frequencies ranging from 0.01 to 10 Hz using fixed, ±1 V sinusoidal excitation. Polypyrrole length sensors were evaluated using a thin-film dynamic mechanical analyzer for the same range of frequencies with a 2% sinusoidal input strain. Polypyrrole supercapacitors were evaluated using cyclic voltammetry (−1.0 V to +1.0 V; 12.5 to 100 mV/sec) and galvanostatic charge-discharge cycling (0.5 to 2 mA/mg). As an actuator, polypyrrole samples showed measureable actuation strain between 0.001% and 1.6% for the frequency range tested, with amplitude versus frequency decay behavior similar to a first-order low-pass filter. As a length sensor, polypyrrole samples showed linearelastic behavior up to 3% strain and gauge factors near 4. As a symmetric supercapacitor, polypyrrole had capacitance values higher than 20 kF/kg, energy densities near 20 kJ/kg, and power densities near 2 kW/kg. The evaluation of each component, independently, justified creating a cooperative system composed of these three components operating simultaneously. Polypyrrole supercapacitors provided ample power to excite polypyrrole actuators. Polypyrrole length sensors attached in series to polypyrrole actuators were capable of measuring strain from coupled polypyrrole actuators. Performance metrics and future possibilities regarding conducting polymer-based multifunctional materials are discussed.
Conducting polymers such as polypyrrole, polythiophene and polyaniline are currently studied as novel biologically inspired actuators. The actuation mechanism of these materials depends upon the motion of ions in and out of the polymer film during electrochemical cycling. The diffusion of ions into the bulk of the film causes the dynamic mechanical compliance (or modulus) of the material to change during the actuation process. The mechanism of this change in compliance is not fully understood as it can depend on many different factors such as oxidation state, solvation of the film and the level of counter ion swelling. In-situ measurement of the dynamic compliance of polypyrrole as a function of charge is difficult since the compliance depends upon the excitation frequency as well as the electrochemical stimulus. Pytel et al [1] studied the effect of the changing elastic modulus in-situ at a fixed frequency. In this study we describe a technique to measure the compliance response of polypyrrole as a function of frequency and electrochemistry. A voltage input and a simultaneous stress input was applied to polypyrrole actuated in neat 1butyl-3-methylimidazolium hexaflourophosphate. The stress input was a stochastic force with a bandwidth of 30 Hz and it allows us to compute the mechanical compliance transfer function of polypyrrole as function of the electrochemistry. Our studies show that the low frequency compliance changes by 50% as charge was injected into the polymer. The compliance changes reversibly as ions diffuse in and out of the film which indicates that the compliance depends upon the level of counter ion swelling.
Conducting polymer actuators such as polypyrrole can generate stresses over 10 times larger than skeletal muscle and have typical repeatable strains between 1% and 12%, making them potential candidates for lightweight, low-cost, robotic applications. Polypyrrole linear actuators under closed loop control have not been previously reported. Here we report the open and closed loop performance of polypyrrole linear contractile actuators evaluated at pre-loaded stresses of 1 MPa to 3 MPa. A standard PI control scheme driving a potentiostat was implemented in conjunction with positioning feedback from a DC/DC linear variable differential transformer (LVDT). A dynamic positioning range of 3400 is reported, with a positioning resolution of 125 nm (0.001% strain) and a maximum repeatable displacement of 427 microns (3.6% strain). The open loop frequency response of actuator strain shows characteristics of a first-order low pass filter with a log gain versus log frequency slope near -1 for frequencies tested between 0.05 Hz to 2 Hz. The closed loop frequency response of actuator strain when tracking a sinusoidal set-point signal of 0.5% strain shows characteristics of a first order system with one zero, with a corner frequency near 0.08 Hz and an operating bandwidth up to 1 Hz.Step responses at various controller output maximum voltages show a reduction in contractile response times by a factor of four, where higher voltages yield faster contractile responses.
Design and development of a masticatory robot to measure the forces acting on teeth during mastication. Piezoelectric film bed will be used to measure the forces acting on tooth during mastication. On top of the piezoelectric film bed the lower jaw tooth will be mounted. The lower jaw will be having the upward and downward motion whereas the teeth on the upper jaw will remain fixed. Load cells will be placed on the upper jaw. Load cells would help in recording the forces acting on teeth during mastication of food. During mastication of food, due to chewing of food, the piezoelectric film bed will be deformed which will produce an electric charge that can be mathematically modelled into force by using Labview software.
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