[1] The 0.3-to 26-mm reflectance spectra of a suite of 28 zeolites were measured and analyzed to derive spectral-compositional-structural relationships. Below $7 mm, the spectra are largely dominated by absorption features associated with zeolitic water. At longer wavelengths, the spectra are dominated by absorption features associated with the aluminosilicate framework. The spectra exhibit a number of systematic variations which can be used for both structural and compositional determinations. These include: (1) distinguishing different structural groups on the basis of wavelength position variations associated with absorption features in the 8.5-to 26-mm region that are related to differences in the structure of the aluminosilicate framework; (2) determining the major cation which is present (Ca, Na, K) and the associated electronic environment of the zeolitic water on the basis of how these cations hydrogen bond to the water molecules in the void spaces and consequently affect water-related absorption band positions, particularly in the 1.4, 1.9, and 2.0-to 2.5-mm regions; (3) determining the Al:(Al + Si) ratio and SCFM chemical index on the basis of absorption features in the 7-to 26-mm region which are most sensitive to these compositional variations; and (4) identifying ironbearing zeolites on the basis of absorption features in the 0.35-to 0.9-mm region. The wavelength position and number of H 2 O-associated absorption bands are sensitive to factors such as the type of major cation, degree of hydrogen bonding, and size of the void space, all of which are somewhat interrelated.
AGU is a participant in a U.S. National Science Foundation (NSF)–funded project called Advancing Ways of Awarding Recognition in Disciplinary Societies (AWARDS), which seeks to examine whether gender bias affects selection of recipients of society awards. AGU is interested in learning why there is a higher proportion of female recipients of service and education awards over the past 2 decades. Combined with a lower rate of receipt of research awards, these results suggest that implicit (subconscious) bias in favor of male candidates still influences awardee selection. Six other professional societies (American Chemical Society, American Mathematical Society, American Society of Anesthesiologists, Mathematical Association of America, Society for Neuroscience, and Society for Industrial and Applied Mathematics) are participating in the project. Volunteers from each participant society attended an Association for Women in Science (AWIS)–sponsored workshop in May 2010 to examine data and review literature on best practices for fair selection of society awardees. A draft proposal for implementing these practices will be brought before the AGU Council and the Honors and Recognition Committee at their upcoming meetings.
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