Single and mixed phase Cu2O/CuO nanorod arrays prepared by thermal oxidation were tested for photocatalysis and photoelectrochemical properties.

Both Fe2O3 thin films and nanorod arrays are deposited using electron beam evaporation through normal thin film deposition and oblique angle deposition (OAD) and are characterized structurally, optically, and photocatalytically. The morphologies of the thin films are found to be arrays of very thin and closely packed columnar structures, while the OAD films are well-aligned nanorod arrays. All films were determined to be in the hematite phase (α-Fe2O3), as confirmed by both structural and optical characterization. Texture measurements indicate that films have similar growth modes where the [110] direction aligns with the direction of material growth. Under visible light illumination, the thin film samples were more efficient at photocatalytically degrading methylene blue, while the nanorod arrays were more efficient at inactivating E. coli O157:H7. The size of the targeted agent and the different film morphologies result in different reactant/surface interactions, which is the main factor that determines photoactivity. Furthermore, an analytic mathematical model of bacterial inactivation based on chemotactic bacterial diffusion and surface deactivation is developed to quantify and compare the inactivation rate of the samples. These results indicate that α-Fe2O3 nanorods are promising candidates for antimicrobial applications and are expected to provide insight into the development of better visible-light antimicrobial materials for food products and processing environments, as well as other related applications.

Using a unique oblique angle co-deposition technique, well-aligned arrays of Ag nanoparticle embedded TiO2 composite nanorods have been fabricated with different concentrations of Ag. The structural, optical, and photocatalytic properties of the composite nanostructures are investigated using a variety of experimental techniques and compared with those of pure TiO2 nanorods fabricated similarly. Ag nanoparticles are formed in the composite nanorods, which increase the visible light absorbance due to localized surface plasmon resonance. The Ag concentrations and the annealing conditions are found to affect the size and the density of Ag nanoparticles and their optical properties. The Ag nanoparticle embedded TiO2 nanostructures exhibit enhanced photocatalytic activity compared to pure TiO2 under visible- or UV-light illumination. Ag plays different roles in assisting the photocatalysis with different light sources. Ag can be excited and can inject electrons to TiO2, working as an electron donor under visible light. While under UV illumination, Ag acts as an electron acceptor to trap the photogenerated electrons in TiO2. Due to the opposite electron transfer direction under UV and visible light, the presence of Ag may not result in a greater enhancement in the photocatalytic performance.

Using the difference of the polarization transmission spectra of elliptical nanohole arrays (ENAs), the figure of merit (FOM) of the sensor performance of ENA can be significantly improved, and is inversely proportional to the measurement resolution. By optimizing the aspect ratio of the elliptical holes, Ag thickness, substrate-effect, and adhesive layer, the sensitivity, FOM, and relative sensitivity of the ENA can be improved to be 775 nm RIU, 705 RIU, and 70.23%, respectively, with an excellent linear dependence on the change of refractive index. Such a high-performance sensor also can be used in monitoring the molecule adsorption and RNA hybridization, revealing a highly localized near-field enhancement. This will benefit the sensing of surface-specific binding events in biologic detection and medical diagnosis.